Co-ordination of copper(II) and nickel(II) ions by a novel open chain oxime ligand

Abstract

Potentiometric spectroscopic and X-ray studies of the open chain oxime ligand, N,N′-bis(2-hydroxyimino-propionyl)propane-1,3-diamine and its complexes with Ni^II and Cu^II ions showed a very high efficacy of the ligand studied in the co-ordination of both Cu^II and Ni^II ions. The metal complexes are very stable and square-planar with four nitrogens involved in metal-ion binding. These complexes may be additionally stabilised by hydrogen bonds between two oxime oxygen atoms.

References

1. C. O. Onindo, T. Yu. Sliva, T. Kowalik-Jankowska, I. O. Fritsky, P. Buglyo, L. D. Pettit, H. Kozłowski and T. Kiss, J. Chem. Soc., Dalton Trans., 1995, 3911.
2. T. Yu. Sliva, T. Kowalik-Jankowska, V. M. Amirkhanov, T. Głowiak, C. O. Onindo, I. O. Fritsky and H. Kozłowski, J. Inorg. Biochem., 1997, 65, 287.
3. B. Kurzak, H. Kozłowski and E. Farkas, Coord. Chem. Rev., 1992, 114, 169.
4. V. Yu. Kukushkin, D. Tudela and A. J. L. Pombeiro, Coord. Chem. Rev., 1996, 156, 333.
5. R. Ruiz, J. Sanz, B. Cervera, F. Lloret, M. Julve, C. Bois, J. Faus and M. Carmen Munoz, J. Chem. Soc., Dalton Trans., 1993, 1623.
6. D. Mansuy, P. Battioni and J.-P. Battioni, Eur. J. Biochem., 1989, 184, 267; B. Meunier, Chem. Rev., 1991, 92, 1411.
7. J. Custot, J.-L. Boucher, S. Vadon, C. Guedes, S. Dijols, M. Delaforge and D. Mansuy, J. Biol. Inorg. Chem., 1995, 1, 73.
8. T. Yu. Sliva, A. M. Duda, T. Głowiak, I. O. Fritsky, V. M. Amirkhanov, A. A. Mokhir and H. Kozłowski, J. Chem. Soc., Dalton Trans., 1997, 273.
9. H.-P. Lau and C. D. Gutsche, J. Am. Chem. Soc., 1978, 100, 1857.
10. H. M. Irving, M. H. Miles and K. D. Pettit, Anal. Chim. Acta, 1967, 68, 475.
11. P. Gans, A. Sabatini and A. Vacca, J. Chem. Soc., Dalton Trans., 1985, 1195.
12. G. M. Sheldrick, Acta Crystallogr., Sect. A, 1990, 46, 467.
13. G. M. Sheldrick, SHELXL 93, University of Göttingen, 1993.
14. International Tables for Crystallography, Kynoch Press, Birmingham, 1974, vol. 4.
15. R. Charles and H. Freuer, Anal. Chim. Acta, 1954, 11, 101.
16. Ya. D. Lampeka, A. V. Perikhod'ko, A. Yu. Nazarenko and E. B. Rusanov, J. Chem. Soc., Dalton Trans., 1996, 2017; I. F. Maloshtan and Ya. D. Lampeka, Zh. Neorg. Khim., 1996, 41, 1845.
17. G. E. Jackson and B. S. Nakani, J. Chem. Soc., Dalton Trans., 1996, 1373.
18. M. S. Hussain and E. O. Schlemper, Inorg. Chem., 1979, 18, 2275.
19. H. Sigel and R. B. Martin, Chem. Rev., 1982, 82, 385.
20. Yu. A. Simonov, A. A. Dvorkin, T. I. Malinowsky, E. E. Gubina, R. D. Lampeka and I. O. Fritsky, Izv. Akad. Nauk Mold. SSR, Ser. Biol. Chim. Nauk, 1992, 1, 16.
21. R. D. Lampeka, A. A. Dvorkin, Yu. A. Simonov, I. O. Fritsky and V. V. Skopenko, Ukr. Khim. Zh. (Russ. Edition), 1989, 55, 458; A. A. Dvorkin, I. O. Fritsky, Yu. A. Simonov, R. D. Lampeka, M. D. Mazus and T. I. Malinowsky, Dokl. Akad. Nauk SSSR, 1990, 310, 87; A. A. Dvorkin, Yu. A. Simonov, V. V. Skopenko, I. O. Fritsky and R. D. Lampeka, Dokl. Akad. Nauk. SSSR, 1990, 313, 98; V. Kh. Kravtsov, O. N. Rebrova, Yu. A. Simonov, R. D. Lampeka and I. O. Fritskii, Russ. J. Inorg. Chem. (Engl. Transl.), 1992, 37, 743.
22. I. O. Fritsky, R. D. Lampeka, V. V. Skopenko, Yu. A. Simonov, A. A. Dvorkin and T. I. Malinowsky, Z. Naturforsch., Teil B, 1993, 48, 270.
23. Yu. A. Simonov, V. Kh. Kravtsov, I. O. Fritskii, E. E. Gubina, R. D. Lampeka, T. S. Iskenderov and A. Zh. Zhumabaev, Koord. Khim., 1995, 21, 407.
24. I. O. Fritsky, R. D. Lampeka, V. Kh. Kravtsov and Yu. A. Simonov, Acta Crystallogr., Sect. C, 1993, 49, 1041; I. O. Fritsky, R. D. Lampeka, V. V. Skopenko, Yu. A. Simonov and A. A. Dvorkin, Russ. J. Inorg. Chem. (Engl. Transl.), 1994, 39, 771.