Mercury–carbon bond formation promoted by the co-ordinated ligand reaction of a β-diiminate chelate

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Takashi Kajiwara, Reiko Murao and Tasuku Ito


Abstract

Reaction between [Ni(tmtaa)] and HgBr2 in dichloroethane afforded the mercury–carbon bonded tetranuclear complex [Ni(tmtaa)HgBr]2[Hg2Br6] (H2tmtaa = 5,14-dihydro-6,8,15,17- tetramethyldibenzo[b,i][1,4,8,11] tetraazacyclotetradecine).


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