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DOI: 10.1039/A702807E (Paper) Reference Section for: J. Chem. Soc., Dalton Trans., 1997, 2215-2216

Reactions of molecular CaF2 with [(C5Me5)TiF3] and [(C5Me4Et)TiF3]: symbiosis between ionic solids and organometallic compounds

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Andrej Pevec, Alojz Demsar, Volker Gramlich, Sasa Petricek and Herbert W. Roesky

Abstract

The reaction between [(C5Me5)TiF3] or [(C5Me4Et)TiF3] respectively in the presence of CaF2 (prepared in situ) resulted in the formation of [{(C5Me5)TiF3}4 CaF2] 1 or [{(C5Me4Et)TiF3}4 CaF2] 2, an X-ray study of compound 2 showed it to possess a core analogous to a crown ether.

References

  1. B. Dietrich, P. Viout and J.-M. Lehn, Macrocyclic Chemistry, VCH, Weinheim, 1993 Search PubMed.
  2. J.-M. Lehn, Supramolecular Chemistry, VCH, Weinheim, 1995 Search PubMed.
  3. A. Müller, H. Reuter and S. Dillinger, Angew. Chem., 1995, 107, 2505; Angew. Chem., Int. Ed. Engl., 1995, 34, 2328 Search PubMed.
  4. H. Plenio, Angew. Chem., 1997, 109, 358; Angew. Chem., Int. Ed. Engl., 1997, 36, 348 Search PubMed.
  5. H. W. Roesky, M. Sotoodeh and M. Noltemeyer, Angew. Chem., 1992, 104, 869 CAS; Angew. Chem., Int. Ed. Engl., 1992, 31, 864 Search PubMed; F.-Q. Liu, D. Stalke and H. W. Roesky, Angew. Chem., 1995, 107, 2004 Search PubMed; Angew. Chem., Int. Ed. Engl., 1995, 34, 1872; F.-Q. Liu, A. Kuhn, R. Herbst-Irmer, D. Stalke and H. W. Roesky, Angew. Chem., 1994, 106, 577; Angew. Chem., Int. Ed. Engl., 1994, 33, 555 Search PubMed; A. Künzel, H. W. Roesky, M. Noltemeyer and H.-G. Schmidt, J. Chem. Soc., Chem. Commun., 1995, 2145 Search PubMed; A. Voigt, R. Murugavel, M. L. Montero, H. Wessel, F.-Q. Liu, H. W. Roesky, J. Usòn, T. Albers and E. Parisini, Angew. Chem., 1997, 109, 1020 CAS; Angew. Chem., Int. Ed. Engl., 1997, 36, 1001 Search PubMed.
  6. M. Sotoodeh, I. Leichtweis, H. W. Roesky, M. Noltemeyer and H.-G. Schmidt, Chem. Ber., 1993, 126, 913 CrossRef CAS; A. Herzog, F.-Q. Liu, H. W. Roesky, A. Demsar, K. Keller, M. Noltemeyer and F. Pauer, Organometallics, 1994, 13, 1251 CrossRef CAS.
  7. S.-H. Wu, Z.-B. Ding and X.-J. Li, Polyhedron, 1994, 13, 2679 CrossRef CAS.
  8. E. F. Murphy, T. Lübben, A. Herzog, H. W. Roesky, A. Demsar, M. Noltemeyer and H.-G. Schmidt, Inorg. Chem., 1996, 35, 23 CrossRef CAS.
  9. E. Mason and H. A. Eick, Acta Crystallogr., Sect. B, 1982, 38, 1821 CrossRef; B. B. Hughes, R. C. Haliwanger, C. G. Pierpont, M. Hampton and G. L. Blackmer, Inorg. Chem., 1980, 19, 1801 CrossRef CAS.
  10. G. M. Sheldrick, SHELXTL PLUS, Siemens Analytical X-Ray Instruments Inc., Madison, WI, 1990; SHELXL 93, University of Göttingen, 1993.
  11. B. G. Hyde and S. Andersson, Inorganic Crystal Structures, Wiley, 1st edn., New York, 1989, p. 187 Search PubMed.
  12. H. G. von Schnering, D. Vu and K. Peters, Z. Kristallogr., 1983, 165, 305 CAS.
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