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DOI: 10.1039/A702287E (Paper) Reference Section for: J. Chem. Soc., Dalton Trans., 1997, 2383-2384

Construction of a new open-framework solid from 1,3,5-cyclohexanetricarboxylate and zinc(II) building blocks

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Omar M. Yaghi, Ryan Jernigan, Hailian Li, Charles E. Davis and Thomas L. Groy

Abstract

Addition copolymerization of cis,cis-1,3,5-cyclohexanetricarboxylate (CTC) with zinc(II) at 25 °C yielded the extended co-ordination solid, Zn3[(CTC)(C5H5N)]2· 2(CH3)2NC(O)H, which has one-dimensional channels with an aperture of nearly 6 Å as found by an X-ray crystallographic study.

References

  1. See, for example, C. L. Bowes and G. A. Ozin, Adv. Mater., 1996, 8, 13 Search PubMed; D. Venkataraman, S. Lee, J. S. Moore, P. Zhang, K. A. Hirsch, G. B. Gardner, A. C. Covey and C. L. Prentice, Chem. Mater., 1996, 8, 2030 CAS; F. Robinson and M. J. Zaworotko, J. Chem. Soc., Chem. Commun., 1995, 23, 2413 CrossRef CAS; O. M. Yaghi, in Access in Nanoporous Materials, eds. T. J. Pinnavaia and M. F. Thorpe, 1995, Plenum, New York, p. 111 RSC; T. Bein, Supramolecular Architecture: Synthetic Control in Thin Films and Solids, American Chemical Society, Washington, DC, 1992 RSC; T. Iwamoto, in Inclusion Compounds, eds. J. L. Atwood, J. E. D. Davies and D. D. MacNicol, 1991, Oxford, New York, vol. 5, pp. 177–212 RSC; B. F. Hoskins and R. Robson, J. Am. Chem. Soc., 1990, 112, 1546 RSC; A. Michaelides, V. Kiritsis, S. Skoulika and A. Aubry, Angew. Chem., Int. Ed. Engl., 1993, 32, 1495 Search PubMed; S. O. H. Gutschke, M. Molinier, A. K. Powell, R. E. P. Winpenny and P. T. Wood, Chem. Commun., 1996, 823 Search PubMed.
  2. O. M. Yaghi and H. Li, J. Am. Chem. Soc., 1996, 118, 295 CrossRef CAS; O. M. Yaghi and H. Li, J. Am. Chem. Soc., 1995, 117, 10 401 CrossRef CAS; D. Ramprasad, G. P. Pez, B. H. Toby, T. J. Markley and R. M. Pearlstein, J. Am. Chem. Soc., 1995, 117, 10 694 CrossRef CAS; D. Venkataraman, G. B. Gardner, S. Lee and J. S. Moore, J. Am. Chem. Soc., 1995, 117, 11 600 CrossRef.
  3. (a) O. M. Yaghi, C. Davis, G. Li and H. Li, J. Am. Chem. Soc., 1997, 119, 2861 CrossRef CAS; (b) O. M. Yaghi, H. Li and T. L. Groy, J. Am. Chem. Soc., 1996, 118, 9096 CrossRef CAS; (c) O. M. Yaghi, G. Li and H. Li, Nature (London), 1995, 378, 703 CrossRef CAS.
  4. J. Rebek, jun., B. Askew, M. Killoran, D. Nemeth and F.-T. Lin, J. Am. Chem. Soc., 1987, 109, 2426 CrossRef and refs. therein.
  5. G. M. Sheldrick, SHELXTL PLUS, Program package for structure solution and refinement, version 4.2, Siemens Analytical X-Ray Instruments, Madison, WI, 1990.
  6. R. H. Prince, in Comprehensive Coordination Chemistry, ed. G. Wilkinson, Pergamon, Oxford, 1987, vol. 5, p. 966 Search PubMed.
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