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DOI: 10.1039/A702146A (Paper) Reference Section for: J. Chem. Soc., Dalton Trans., 1997, 1801-1804

Extended networks via hydrogen bond cross-linkages of [M(bipy)] (M = Zn2+ or Fe2+; bipy = 4,4′-bipyridyl) linear co-ordination polymers

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Lucia Carlucci, Gianfranco Ciani, Davide M. Proserpio and Angelo Sironi

Abstract

Both co-ordinative and hydrogen bonds contribute to networking in a series of polymeric compounds based on [M(bipy)] (bipy = 4,4′-bipyridyl) linear chains, which, through metal-co-ordinated water molecules and solvated bipy bases, have been shown to be cross-linked by single or double hydrogen-bond bridges of the type M–H2O · · · bipy · · · H2O–M, producing extended frames.

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