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DOI: 10.1039/A702091K (Paper) Reference Section for: J. Chem. Soc., Dalton Trans., 1997, 1793-1794

Three-dimensional structure of the clathrate complex [{Ni(NCS)2(H2O)2(dabco)2 }·dabco]·2dmso obtained from zero valent metal (dabco = 1,4-diazabicyclo[2.2.2]octane and dmso = dimethyl sulfoxide)

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Svitlana R. Petrusenko, Volodymyr N. Kokozay, Olga Yu. Vassilyeva and Brian W. Skelton

Abstract

The new clathrate complex [{Ni(NCS)2(H2O)2(dabco)2 }· dabco]·2dmso (dabco = 1,4-diazabicyclo[2.2.2]octane and dmso = dimethyl sulfoxide), the first example of a compound comprising metal centres and dabco molecules in a 1[hair space]:[hair space]3 ratio, has been prepared from metal powder; its crystal structure contains [Ni(NCS)2(H2O)2(dabco)2] ∞ square grids linked by hydrogen-bonded dabco molecules to afford a three-dimensional framework, molecules of dmso occupy square-shaped channels.

References

  1. See, for example, S. Subramanian and M. J. Zaworotko, Angew. Chem., Int. Ed. Engl., 1995, 34, 2127 Search PubMed ; S. Kawata, S. Kitagawa, M. Kondo, I. Furuchi and M. Munakata, Angew. Chem., Int. Ed. Engl., 1994, 33, 1759 CrossRef CAS ; O. Kahn, Molecular Magnetism, VCH, New York, 1993 CrossRef ; J. Kim, D. Whang, Y.-S. Koh and K. Kim, J. Chem. Soc., Chem. Commun., 1994, 637 CrossRef .
  2. S. R. Petrusenko, I. Sieler and V. N. Kokozay, Z. Naturforsch., Teil B, in the press Search PubMed .
  3. V. N. Kokozay, Yu. A. Simonov, S. R. Petrusenko and A. Dvorkin, Zh. Neorg. Khim., 1990, 35, 2839 Search PubMed .
  4. H. Yuge and T. Iwamoto, Acta Crystallogr., Sect. C, 1995, 51, 374 CrossRef .
  5. W. R. Busing and H. A. Levy, Acta Crystallogr., 1967, 22, 457 CrossRef CAS .
  6. S. R. Hall, G. S. D. King and J. M. Stewart, XTAL 3.4. User's Manual, University of Western Australia, 1995 Search PubMed .
  7. S. M. Godfrey, C. A. McAuliffe and R. G. Pritchard, J. Chem. Soc., Dalton Trans., 1993, 2875 RSC ; A. D. Garnovskii, B. I. Kharisov, G. Gojon-Zorrilla and D. A. Garnoskii, Russ. Chem. Rev. (Engl. Transl.), 1995, 64, 201 Search PubMed ; S. R. Petrusenko, V. N. Kokozay and I. O. Fritsky, Polyhedron, 1997, 16, 267 CrossRef CAS .
  8. A. B. P. Lever, Inorganic Electron Spectroscopy, Elsevier, Amsterdam, 1984 Search PubMed .
  9. S. Batsanov, Zh. Neorg. Khim., 1991, 36, 3015 Search PubMed .
  10. L. Sacconi, F. Mani and A. Bencini, Comprehensive Coordination Chemistry, eds. G. Wilkinson, R. D. Gillard and J. A. McCleverty, Pergamon, Oxford, 1987, vol. 5, p. 71 Search PubMed .
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