Heterometallic complexes containing d- and f-block elements: synthesis and structural characterisation of novel Ni–Er and Co–Dy compounds

(Note: The full text of this document is currently only available in the PDF Version )

Euan K. Brechin, Steven G. Harris, Simon Parsons and Richard E. P. Winpenny


Abstract

The structures of new heterometallic tetranuclear complexes have been determined which each feature two 3d-metal centres, either Co or Ni, and two 4f-metal sites; preliminary magnetic data have also been reported.


References

  1. A. Bencini, C. Benelli, A. Caneschi, R. L. Carlin, A. Dei and D. Gatteschi, J. Am. Chem. Soc., 1985, 107, 8128 CrossRef CAS; C. Benelli, A. Caneschi, D. Gatteschi, O. Guillou and L. Pardi, Inorg. Chem., 1990, 29, 1751 and refs. therein.
  2. N. Matsumato, M. Sakamoto, H. Tamaki, H. Okawa and S. Kida, Chem. Lett., 1989, 853.
  3. M. Andruh, I. Ramade, E. Codjovi, O. Guillou, O. Kahn and J. C. Trombe, J. Am. Chem. Soc., 1993, 115, 1822 CrossRef CAS and refs. therein.
  4. A. J. Blake, R. O. Gould, C. M. Grant, P. E. Y. Milne, S. Parsons and R. E. P. Winpenny, J. Chem. Soc., Dalton Trans., 1997, 485 RSC and refs. therein.
  5. S. Wang, S. J. Trepanier and M. J. Wagner, Inorg. Chem., 1993, 32, 833 CrossRef CAS.
  6. C. Benelli, A. J. Blake, P. E. Y. Milne, J. M. Rawson and R. E. P. Winpenny, Chem. Eur. J., 1995, 1, 614 CrossRef CAS.
  7. J.-P. Costes, F. Dahan, A. Dupuis and J.-P. Laurent, Inorg. Chem., 1996, 35, 2400 CrossRef CAS.
  8. X.-M. Chen, Y.-L. Wu, Y.-X. Tong and X.-Y. Huang, J. Chem. Soc., Dalton Trans., 1996, 2443 RSC.
  9. G. B. Deacon, C. M. Forsyth, W. C. Patalinghug, A. H. White, A. Dietrich and H. Schumann, Aust. J. Chem., 1992, 45, 567 CAS; L. F. Lindoy, H. C. Lip, H. W. Louie, M. G. B. Drew and M. J. Hudson, J. Chem. Soc., Chem. Commun., 1977, 778 RSC; J. M. Boncella and R. A. Andersen, J. Chem. Soc., Chem. Commun., 1984, 809 RSC; W. J. Evans, I. Bloom, J. W. Grate, L. A. Hughes, W. E. Hunter and J. L. Atwood, Inorg. Chem., 1985, 24, 4620 CrossRef CAS; J. P. White III, H. Deng, E. P. Boyd, J. Galluci and S. G. Shore, Inorg. Chem., 1994, 33, 1685 CrossRef CAS; D. M. L. Goodgame, S. Menzer, A. T. Ross and D. J. Williams, J. Chem. Soc., Chem. Commun., 1994, 2605 RSC; D. Deng, X. Zheng, C. Qian, J. Sun, A. Dormond, D. Baudry and M. Visseaux, J. Chem. Soc., Dalton Trans., 1994, 1665 RSC.
  10. J.-F. Petit, J. C. Trombe, A. Gleizes and J. Galy, C. R. Acad. Sci., Ser. 2, 1987, 304, 1117 Search PubMed and refs. therein.
  11. A. J. Blake, E. K. Brechin, A. Codron, R. O. Gould, C. M. Grant, S. Parsons, J. M. Rawson and R. E. P. Winpenny, J. Chem. Soc., Chem. Commun., 1995, 1983 RSC.
  12. G. M. Sheldrick, SHELXS 86, Acta Crystallogr., Sect. A, 1990, 46, 467 CrossRef.
  13. G. M. Sheldrick, SHELXL 93, University of Göttingen, 1993.
  14. Y. Yukawa, S. Igarashi, A. Yamano and S. Sato, Chem. Commun., 1997, 711 RSC.
Click here to see how this site uses Cookies. View our privacy policy here.