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DOI: 10.1039/A701397C (Paper) Reference Section for: J. Chem. Soc., Dalton Trans., 1997, 2639-2644

Synthesis and structure of a new layered aluminium phosphate: [BuNH3]3[Al3P4O16]

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Ann M. Chippindale, Andrew R. Cowley, Qisheng Huo, Richard H. Jones, Ashley D. Law, John M. Thomas and Ruren Xu

Abstract

A new two-dimensional aluminium phosphate, [BuNH3]3[Al3P4O16 ], has been synthesized under solvothermal conditions at 453 K using butylamine as template. The structure, solved using single-crystal X-ray diffraction data measured at 200 K [trigonal, space group P[3 with combining macron], a = 13.158(2), c = 9.633(2) Å, U = 1444.4 Å3, Z = 2], consists of AAAA-stacked [Al3P4O16]3- layers containing 12-membered rings of alternating AlO4 and PO4 tetrahedra. Disordered butylammonium cations lie between the layers with their hydrophobic tails pointing into the channels bounded by the 12-membered rings.

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