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DOI: 10.1039/A700484B (Paper) Reference Section for: J. Chem. Soc., Dalton Trans., 1997, 1601-1606

The reactivity of [2.2.2]paracyclophane towards Cr(CO)6: experimental and theoretical considerations

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Paul J. Dyson, David G. Humphrey, John E. McGrady, Priya Suman and Derek Tocher

Abstract

The reactivity of [2.2.2]paracyclophane (C24H24) towards hexacarbonylchromium has been examined and the rates of reaction for the formation of mono-, bis- and tris-complexes established. The structures of [Cr(CO)3(η-C24H24)] and [{Cr(CO)3}2(η-C24H 24)] have been established by single crystal X-ray diffraction. These experimental observations have been interpreted using approximate density functional molecular orbital calculations.

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