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DOI: 10.1039/A700036G (Paper) Reference Section for: J. Chem. Soc., Dalton Trans., 1997, 913-914

Rectangular grid two-dimensional sheets of copper(II) bridged by both co-ordinated and hydrogen bonded 4,4′-bipyridine (4,4′-bipy) in [Cu(µ-4,4′-bipy)(H2O)2(FBF3) 2]·4,4′-bipy

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Alexander J. Blake, Stuart J. Hill, Peter Hubberstey and Wan-Sheung Li

Abstract

The complex [Cu(µ-4,4′-bipy)(H2O)2(FBF3) 2]·4,4′-bipy (4,4′-bipy = 4,4′-bipyridine), in which copper atoms are linked by Cu–4,4′-bipy–Cu and Cu–OH2 [hair space]·[hair space]·[hair space]·[hair space] 4,4′-bipy [hair space]·[hair space]·[hair space]·[hair space] H2O–Cu assemblies, involving co-ordinated and hydrogen bonded 4,4′-bipy, respectively, to form two-dimensional rectangular grid sheets, has been isolated and structurally characterised.

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