Homoleptic tris(diacetoneglucose)phosphite as a novel entry into chiral phosphorus derivatives in organometallic chemistry

Abstract

A novel chiral C₃ phosphite P(odag)₃ (odag = 1,2∶5,6-di-O-isopropylidene- α-D-glucofuranoside) has been synthesized on a large scale; when treated with Cu(CO)Cl it gave the cubane [{CuCl[P(odag)₃]}₄], which is in equilibrium with a dimeric form in solution.

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