View PDF Version
 
DOI: 10.1039/A608357I (Paper) Reference Section for: J. Chem. Soc., Dalton Trans., 1997, 1713-1718

Synthesis and characterisation of ruthenium carbonyl fluorides

(Note: The full text of this document is currently only available in the PDF Version )

Karl S. Coleman, John H. Holloway and Eric G. Hope

Abstract

The oxidative fluorination of [Ru3(CO)12] with XeF2 in anhydrous HF afforded, in solution, cis-[RuF2(CO)4] as the major product with [RuF(CO)5]+, [Ru2F4(CO)7], [{RuF(CO)4}2(µ-F)]+, mer- and fac-[RuF3(CO)3]-, [{RuF2(CO)3}n] and [{RuF2(CO)3}(µ-F){Ru(CO)5 }]+ as minor products, all of which have been characterised by 13C, 19F and 13C-{19F} NMR spectroscopies. Removal of the HF solvent in vacuo yielded tetrameric [{RuF2(CO)3}4].

References

  1. K. G. Caulton, O. Eisenstein, J. T. Poulton, M. P. Sigalas and W. E. Streib, Inorg. Chem., 1994, 33, 1476 CrossRef CAS.
  2. R. G. Bergman, P. Burger and J. E. Veltheer, J. Am. Chem. Soc., 1995, 117, 12478 CrossRef.
  3. M. Ahlgrén, M. Haukka and T. A. Pakkanen, J. Chem. Soc., Dalton Trans., 1996, 1972 Search PubMed.
  4. D. M. Bruce and J. H. Holloway, Transition Met. Chem., 1978, 3, 317 and refs. therein.
  5. S. A. Brewer, J. H. Holloway and E. G. Hope, J. Chem. Soc., Dalton Trans., 1994, 1067 RSC.
  6. S. A. Brewer, A. K. Brisdon, J. H. Holloway, E. G. Hope, L. A. Peck and P. G. Watson, J. Chem. Soc., Dalton Trans., 1995, 2945 RSC.
  7. A. J. Hewitt, J. H. Holloway, R. D. Peacock, J. B. Raynor and I. L. Wilson, J. Chem. Soc., Dalton Trans., 1976, 579 RSC.
  8. C. J. Marshall, R. D. Peacock, D. R. Russell and I. L. Wilson, Chem. Commun., 1970, 1643 RSC.
  9. J. H. Holloway, Chem. Commun., 1966, 22 RSC.
  10. K. O. Christe, W. W. Wilson and C. J. Schack, J. Fluorine Chem., 1978, 11, 711.
  11. W. W. Dukat, J. H. Holloway, E. G. Hope, P. J. Townson and R. L. Powell, J. Fluorine Chem., 1993, 62, 293 CrossRef CAS.
  12. S. A. Brewer, J. H. Holloway and E. G. Hope, J. Fluorine Chem., 1995, 70, 167 CrossRef CAS.
  13. B. F. G. Johnson, R. D. Johnston and J. Lewis, J. Chem. Soc. A, 1969, 792 RSC.
  14. J. Knight and M. J. Mays, J. Chem. Soc. A, 1970, 711 RSC.
  15. A. J. Deeming, B. F. G. Johnson and J. Lewis, J. Chem. Soc. A, 1970, 2967 RSC.
  16. C. Wang, B. Bley, G. Balzer-Jöllenbeck, A. R. Lewis, S. C. Siu, H. Willner and F. Aubke, J. Chem. Soc., Chem. Commun., 1995, 2071 RSC.
Click here to see how this site uses Cookies. View our privacy policy here.