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DOI: 10.1039/A608336F (Paper) Reference Section for: J. Chem. Soc., Dalton Trans., 1997, 1213-1218

Structural diversity in silver salts of hexahalogenocarborane anions, Ag(CB11H6X6) (X = Cl, Br or I)

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Zuowei Xie, Bo-Mu Wu, Thomas C. W. Mak, Janet Manning and Christopher A. Reed

Abstract

Crystal structures have been determined for three Ag(CB11H6X6) compounds (X = Cl, Br or I) crystallized from arene solvents. They are all one-dimensional co-ordination polymers in the solid state with hexahalogenocarborane anions acting as bridging ligands. The co-ordination geometries of these three salts are, however, unique. The type and number of donors to silver(I) varies from one to another and is not particularly predictable.

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