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DOI: 10.1039/A608140A (Paper) Reference Section for: J. Chem. Soc., Dalton Trans., 1997, 1309-1314

Reactions of transition-metal oxo complexes with B(C6F5)3: crystal structures of [V{OB(C6F5)3} (acac)2], [Ti{OB(C6F5)3} (acac)2] and cis-[MoO{OB(C6F5 )3}(acac)2] (acac = acetylacetonate)

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Jane R. Galsworthy, Malcolm L. H. Green, Matthias Müller and Keith Prout

Abstract

The transition-metal oxo complexes [VO(acac)2], [{TiO(acac)2}2] and cis-[MoO2(acac)2] (acac = C5H7O2) reacted with the strong Lewis acid B(C6F5)3 to give the structurally characterized complexes [V{OB(C6F5)3}(acac)2 ], [Ti{OB(C6F5)3}(acac)2 ] and cis-[MoO{OB(C6F5)3} (acac)2]. The M[double bond, length as m-dash]O–B moiety is essentially linear.

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