Synthesis of a series of novel binucleating ligands based on 1,4,7-triazacyclononane and o-, m- and p-xylene: crystal structure of the µ-hydroxy-bridged dicopper(II) complex [Cu2Lm(OH)2][BPh4 ]2 [Lm = α,α′-bis (N-1,4,7-triazacyclononane)-m-xylene]

(Note: The full text of this document is currently only available in the PDF Version )

Louis J. Farrugia, Paul A. Lovatt and Robert D. Peacock


Abstract

The crystal structure and magnetic properties of [Cu2Lm(OH)2][BPh4 ]2 has been determined; Lm is one of three new binucleating ligands based on 1,4,7-triazacyclononane and o-, m- or p-xylene.


References

  1. O. Kahn, Molecular magnetism, VCH, New York and Cambridge, 1993 Search PubMed.
  2. Bioinorganic Chemistry of Copper, ed. K. D. Karlin and Z. Tyeklár, Chapman and Hall, London, 1993 Search PubMed.
  3. M. J. Young and J. Chin, J. Am. Chem. Soc., 1995, 117, 10 577 CrossRef CAS.
  4. D. H. Vance and A. W. Czarnick, J. Am. Chem Soc., 1993, 115, 12 165 CrossRef.
  5. T. J. Atkins, J. Am. Chem. Soc., 1980, 102, 6364 CrossRef CAS.
  6. A. Altomare, G. Cascarno, C. Giacovazza and A. Gualiardi, J. Appl. Crystallogr., 1994, 27, 435 CrossRef.
  7. G. M. Sheldrick, University of Göttingen, 1993.
  8. P. Chaudhuri, D. Ventur, K. Wieghardt, E.-M. Peters and A. Simon, Angew. Chem., Int. Ed Engl., 1985, 24, 57 CrossRef.
  9. L. J. Farrugia, P. A. Lovatt and R. D. Peacock, Inorg. Chim. Acta, 1996, 246, 343 CrossRef CAS.
  10. L. J. Farrugia, P. A. Lovatt and R. D. Peacock, unpublished work.
  11. HYPERCHEM, release 4.5, Hypercube Inc., Ontario.
Click here to see how this site uses Cookies. View our privacy policy here.