View PDF Version
 
DOI: 10.1039/A607334D (Paper) Reference Section for: J. Chem. Soc., Dalton Trans., 1997, 1355-1358

Synthesis of phosphido-bridged dinuclear complexes through sodium reduction of cis-[M{P(C6H11)2 H}2Cl2] (M = Ni or Pd)

(Note: The full text of this document is currently only available in the PDF Version )

Roberto Giannandrea, Piero Mastrorilli, Cosimo Francesco Nobile and Ulli Englert

Abstract

Reduction of cis-[Ni{P(C6H11)2H} 2Cl2] with sodium afforded the dinuclear nickel complex [{Ni[µ-P(C6H11)2][P(C6 H11)2H]}2] which, in turn, reacted with CO producing [{Ni[µ-P(C6H11)2](CO)2 }2]. The reduction of cis-[Pd{P(C6H11)2H} 2Cl2] occurred in two steps giving first [Pd2{µ-P(C6H11)2 }Cl{P(C6H11)2H}3 ], then [{Pd[µ-P(C6H11)2][P(C6 H11)2H]}2]. The structure of the chloride complex was determined.

References

  1. M. Aresta, C. F. Nobile and A. Sacco, Inorg. Chim. Acta, 1975, 12, 167 CrossRef CAS; P. Mastrorilli, G. Moro, C. F. Nobile and M. Latronico, Inorg. Chim. Acta, 1992, 192, 183 CrossRef CAS.
  2. C. F. Nobile, G. Vasapollo, P. Giannoccaro and A. Sacco, Inorg. Chim. Acta, 1981, 48, 261 CrossRef CAS.
  3. (a) P. E. Garrou, Chem. Rev., 1981, 81, 229 CrossRef CAS; (b) A. J. Carty, S. A. Maclaughlin and D. Nucciarone, in Phosphorus-31 NMR Spectroscopy in Stereochemical Analysis, eds. J. G. Verkade and L. D. Quin, VCH, New York, 1987, p. 559 Search PubMed; (c) J. Powell, E. Fuchs, M. R. Gregg, J. Phillips and M. V. R. Steiner, Organometallics, 1990, 9, 387 CrossRef CAS; (d) M. Sommovigo, M. Pasquali, P. Leoni and U. Englert, Inorg. Chem., 1994, 33, 2686 CrossRef CAS.
  4. H. Schäfer, Z. Naturforsch., Teil B, 1979, 34, 1358 Search PubMed.
  5. R. A. Jones, A. L. Stuart, J. L. Atwood, W. E. Hunter and R. D. Rogers, Organometallics, 1982, 1, 1721 CrossRef CAS.
  6. R. A. Jones, A. L. Stuart, J. L. Atwood and W. E. Hunter, Organometallics, 1983, 2, 874 CrossRef CAS.
  7. R. A. Jones, N. C. Norman, M. H. Seeberger, J. L. Atwood and W. E. Hunter, Organometallics, 1983, 2, 1629 CrossRef CAS.
  8. P. Leoni, M. Sommovigo, M. Pasquali, P. Sabatino and D. Braga, J. Organomet. Chem., 1992, 423, 263 CrossRef CAS.
  9. R. G. Hayter, Inorg. Chem., 1964, 3, 711 CrossRef CAS.
  10. P. Leoni, M. Pasquali, T. Beringhelli, G. D'Alfonso and A. P. Minoja, J. Organomet. Chem., 1995, 488, 39 CrossRef CAS.
  11. P. Leoni, M. Pasquali, M. Sommovigo, A. Albinati, F. Lianza, P. S. Pregosin and H. Rüegger, Organometallics, 1994, 13, 4017 CrossRef CAS.
  12. P. Leoni, M. Pasquali, M. Sommovigo, A. Albinati, P. S. Pregosin and H. Rüegger, Organometallics, 1996, 15, 2047 CrossRef CAS.
  13. K. Issleib and G. Doll, Z. Anorg. Allg. Chem., 1960, 305, 1 CrossRef CAS.
  14. H. Goldwhite and A. S. Hirschon, Transition Met. Chem., 1977, 2, 144 CAS.
  15. G. M. Sheldrick, SHELXS 86, Program for the solution of crystal structures, University of Göttingen, 1986.
  16. MOLEN, Molecular Structure Solution Procedure, Enraf-Nonius, Delft, 1990.
Click here to see how this site uses Cookies. View our privacy policy here.