Syntheses, characterization and crystal structures of the boron–antimony adducts BX3·Sb(SiMe3)3 (X = Cl, Br or I)

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Michael S. Lube, Richard L. Wells and Peter S. White


Abstract

The crystal structures of the 1∶1 Lewis acid–base adducts BX3·Sb(SiMe3)3 (X = Cl, Br or I) have been determined and they are the first reported for such boron–antimony adducts.


References

  1. M. S. Lube, R. L. Wells and P. S. White, Inorg. Chem., 1996, 35, 5007 CrossRef CAS.
  2. M. S. Lube, R. L. Wells and P. S. White, Main Group Met. Chem., 1996, 19, 733 Search PubMed.
  3. A. B. Burg and L. R. Grant, J. Am. Chem. Soc., 1959, 81, 1 CrossRef CAS.
  4. M. L. Denniston and D. R. Martin, J. Inorg. Nucl. Chem., 1974, 36, 2175 CrossRef CAS.
  5. D. C. Mente, J. L. Mills and R. E. Mitchell, Inorg. Chem., 1975, 14, 123 CrossRef CAS.
  6. D. C. Mente and J. L. Mills, Inorg. Chem., 1975, 14, 1862 CrossRef CAS.
  7. S. Hoste, D. F. van de Vondel and G. P. van der Kelen, J. Electron Spectros. Rel. Phenom., 1979, 17, 191 Search PubMed.
  8. S. A. Jasper, S. Roach, J. N. Stipp, J. C. Huffman and L. J. Todd, Inorg. Chem., 1993, 32, 3072 CrossRef CAS.
  9. E. Amberger and R. W. Salazar, J. Organomet. Chem., 1967, 8, 111 CrossRef CAS.
  10. C. K. Johnson, ORTEP, A Fortran Thermal Ellipsoid Plot Program, Technical Report ORNL-5138, Oak Ridge, TN, 1976.
  11. See, E. J. Gabe, Y. LePage, J. P. Charland, F. L. Lee and P. S. White, J. Appl. Crystallogr., 1989, 22, 384 Search PubMed.
  12. International Tables for X-Ray Crystallography, Kynoch Press, Birmingham, 1974, vol. 4 Search PubMed.
  13. R. J. Gillespie, D. A. Humphreys, N. C. Baird and E. A. Robinson, Chemistry, Allyn and Bacon, Inc., Boston, 1986, 134 Search PubMed.
  14. R. L. Wells, A. T. McPhail, J. A. Laske and P. S. White, Polyhedron, 1994, 13, 2737 CrossRef CAS.
  15. R. L. Wells, R. A. Baldwin and P. S. White, Organometallics, 1995, 14, 2123 CrossRef CAS.
  16. R. L. Wells, S. R. Aubuchon, S. S. Kher, M. S. Lube and P. S. White, Chem. Mater., 1995, 7, 793 CrossRef CAS.
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