View PDF Version
 
DOI: 10.1039/A606276H (Paper) Reference Section for: J. Chem. Soc., Dalton Trans., 1997, 145-148

Synthesis and structural characterisation of two η1-bonded N-phenylthioformamidate complexes of rhodium

(Note: The full text of this document is currently only available in the PDF Version )

Patricia A. McEneaney, Trevor R. Spalding and George Ferguson

Abstract

The complexes [3-{η1-SC(H)NPh}-3,3-(PMe2Ph)2 -3,1,2-closo-RhC2B9H11] and [2-{η1-SC(H)NPh}-2,2-(PMe2Ph)2 -2,1-closo-RhTeB10H10] have been structurally characterised using X-ray crystallography and are the first η1-bonded thioformamidate complexes to be isolated.

References

  1. W. Mei, L. Shiwei, B. Meizhi and G. Hefu, J. Organomet. Chem., 1993, 447, 227 CrossRef.
  2. G. Ferguson, D. O'Connell and T. R. Spalding, Acta Crystallogr., Sect. C, 1994, 50, 1432 CrossRef.
  3. E. S. Raper, Coord. Chem. Rev., 1996, 153, 199 CrossRef CAS.
  4. G. Ferguson, J. Pollock, P. A. McEneaney, D. P. O'Connell, T. R. Spalding, J. F. Gallagher, R. Maciás and J. D. Kennedy, Chem. Commun., 1996, 679 RSC.
  5. E. J. Gabe, Y. LePage, J. P. Charland, F. J. Lee and P. S. White, J. Appl. Crystallogr., 1989, 22, 384 CrossRef.
  6. G. M. Sheldrick, SHELXL 93, A program for the refinement of crystal structures, University of Göttingen, 1993.
  7. C. K. Johnson, ORTEPII, Report ORNL-5138, Oak Ridge National Laboratory, Oak Ridge, TN, 1976.
  8. A. L. Spek, Molecular Graphics Program, University of Utrecht, 1994.
  9. A. G. Orpen, L. Brammer, F. H. Allen, O. Kennard, D. G. Watson and R. Taylor, in Structure Correlation, eds. H.-B. Burgi and J. D. Dunitz, VCH, Weinheim, 1994, vol. 2, Appendix Search PubMed.
  10. V. I. Minkin, I. D. Sadekov, A. A. Maksimenko, O. E. Kompan and Yu. T. Struchkov, J. Organomet. Chem., 1991, 402, 331 CrossRef CAS.
  11. N. Al-Salim, T. A. Hamor and W. R. McWhinnie, J. Chem. Soc., Chem. Commun., 1986, 453 RSC.
  12. Faridoon, M. McGrath, T. R. Spalding, X. L. R. Fontaine, J. D. Kennedy and M. Thornton-Pett, J. Chem. Soc., Dalton Trans., 1990, 1819 RSC.
  13. Faridoon, O. Ni Dhubhghaill, T. R. Spalding, G. Ferguson, B. Kaitner, X. L. R. Fontaine, J. D. Kennedy and D. Reed, J. Chem. Soc., Dalton Trans., 1988, 2739 RSC.
  14. See, for example, M. F. Hawthorne, J. Organomet. Chem., 1975, 100, 97 Search PubMed and refs. therein R. N. Grimes, in Comprehensive Organometallic Chemistry, eds. G. Wilkinson, F. G. A. Stone and E. W. Abel, Pergamon, Oxford, 1982 and refs. therein CrossRef CAS.
Click here to see how this site uses Cookies. View our privacy policy here.