View PDF Version
 
DOI: 10.1039/A605466H (Paper) Reference Section for: J. Chem. Soc., Dalton Trans., 1997, 403-408

A novel tridentate co-ordination mode for the carbonatonickel system

(Note: The full text of this document is currently only available in the PDF Version )

Albert Escuer, Ramon Vicente, Sujit B Kumar, Xavier Solans and Mercé Font-Bardía

Abstract

The trinuclear compound [Ni2(µ-CO3)(dmpd)4(H2 O)][Ni(dmpd)2(H2O)2][ClO4 ]4·H2O was obtained from the reaction of basic solutions of nickel(II) perchlorate and 2,2-dimethylpropane-1,3-diamine (dmpd) with atmospheric CO2. It crystallises in the orthorhombic system, space group Pcab, with a = 18.634(10), b = 25.447(8), c = 25.598(4) Å, Z = 8, R = 0.0437. The three nickel atoms show octahedral co-ordination with three different environments, Ni(CO3-O,O′)(dmpd)2, Ni(CO3-O″)(dmpd)2(H2O) and Ni(dmpd)2(H2O)2. The carbonate anion acts as a bridge between two nickel ions whereas the [Ni(dmpd)2(H2O)2]2+ subunit is linked by hydrogen bonds to the dinuclear group. The dinuclear [Ni2(µ-CO3)(dmpd)4(H2O)] 2+ subunit shows a moderately weak antiferromagnetic coupling with a J value of -7.8 cm-1. The tridentate co-ordination mode found in the carbonate ligand has not previously been reported for nickel. Its magnetic behaviour is discussed.

References

  1. H. Harada, M. Kodera, G. VucKovic, N. Matsumoto and S. Kida, Inorg. Chem., 1991, 30, 1190 CrossRef CAS; N. Arulsamy, P. A. Goodson, D. J. Hodgson, G. Glerup and K. Michelsen, Inorg. Chim. Acta, 1994, 216, 21 CrossRef CAS; L. Spiccia, G. D. Fallon, A. Markiewicz, K. S. Murray and H. Riesen, Inorg. Chem., 1992, 31, 1066 CrossRef CAS; G. Fachinetti and C. Floriani, J. Am. Chem. Soc., 1979, 101, 1767 CrossRef CAS; T. C. W. Mak, P. Li, C. Zheng and K. Huang, J. Chem. Soc., Chem Commun., 1986, 1597 RSC; R. Alvarez, J. L. Atwood, E. Carmona, P. J. Perez, M. L. Poveda and R. D. Rogers, Inorg. Chem., 1991, 30, 1493 CrossRef CAS.
  2. (a) G. Gattow and J. Zemann, Acta Crystallogr., 1958, 11, 866 CrossRef CAS; (b) D. Y. Jeter, D. J. Hodgson and W. E. Hatfield, Inorg. Chem., 1972, 11, 185 CrossRef CAS; (c) P. C. Healy and A. H. White, J. Chem. Soc., Dalton Trans., 1972, 1913 RSC; (d) P. D. Brotherton and A. H. White, J. Chem. Soc., Dalton Trans., 1973, 2338 RSC; (e) A. K. Gregson and P. C. Healy, Inorg. Chem., 1978, 17, 2969 CrossRef CAS; (f) J. Sletten, Acta Chem. Scand., Ser. A, 1984, 38, 491; (g) G. Kolks, S. J. Lippard and J. V. Waszczak, J. Am. Chem. Soc., 1980, 102, 4832 CrossRef CAS; (h) F. W. B. Einstein and A. C. Willis, Inorg. Chem., 1981, 20, 609 CrossRef CAS.
  3. (a) M. R. Churchill, G. Davies, M. A. El-Sayed and J. P. Hutchinson, Inorg. Chem., 1982, 21, 1002 CrossRef CAS; (b) J. Sletten, H. Hope, M. Julve, O. Kahn, M. Verdaguer and A. Dworkin, Inorg. Chem., 1988, 27, 542 CrossRef CAS; (c) N. Kitajima, T. Koda, S. Hashimoto, T. Kitagawa and Y. Moro-oka, J. Am. Chem. Soc., 1991, 113, 5664 CrossRef CAS; (d) R. Menif, J. Reibenspies and A. E. Martell, Inorg. Chem., 1991, 30, 3446 CrossRef CAS; T. N. Sorrell, W. E. Allen and P. S. White, Inorg. Chem., 1995, 34, 952 CrossRef CAS; (e) P. E. Kruger, G. D. Fallon, B. Moubaraki, K. J. Berry and K. S. Murray, Inorg. Chem., 1995, 34, 4808 CrossRef CAS and refs. therein.
  4. M. Mikuriya, I. Murase, E. Asato and S. Kida, Chem. Lett., 1989, 497 CAS.
  5. S. C. Rawle, C. J. Harding, P. Moore and N. W. Alcock, J. Chem. Soc., Chem. Commun., 1992, 1701 RSC.
  6. R. Kempe, J. Sieler, D. Walther, J. Reinhold and K. Rommel, Z. Anorg. Allg. Chem., 1993, 619, 1105 CrossRef CAS.
  7. K. Yamada, K. Hori and Y. Fukuda, Acta Crystallogr., Sect. C, 1993, 49, 445 CrossRef.
  8. N. Kitajima, S. Hikichi, M. Tanaka and Y. Moro-oka, J. Am. Chem. Soc., 1993, 115, 5496 CrossRef CAS.
  9. A. Escuer, R. Vicente, S. B. Kumar, X. Solans, M. Font-Bardia and A. Caneschi, Inorg. Chem., 1996, 35, 3094 CrossRef CAS.
  10. T. Tanase, S. Nitta, S. Yoshikawa, K. Kobayashi, T. Sakurai and S. Yano, Inorg. Chem., 1992, 31, 1058 CrossRef CAS.
  11. A. Escuer, R. Vicente, E. Peñalba, X. Solans and M. Font-Bardia, Inorg. Chem., 1996, 35, 248 CrossRef CAS.
  12. G. M. Sheldrick, Acta Crystallogr., Sect. A, 1990, 46, 467 CrossRef.
  13. G. M. Sheldrick, SHELXL 93, University of Göttingen, 1993.
  14. International Tables for X-Ray Crystallography, Kynoch Press, Birmingham, 1974, vol. 4, pp. 99–101 and 149 Search PubMed.
  15. C. J. Johnson, ORTEP, Report ORNL-5138, Oak Ridge National Laboratory, Oak Ridge, TN, 1976.
  16. N. F. Curtis, R. W. Hay and Y. M. Curtis, J. Chem. Soc. A, 1968, 182 RSC.
  17. J. Fujita, A. E. Martell and K. Nakamoto, J. Chem. Phys., 1962, 36, 339 CrossRef CAS.
  18. H. Muhonen, Inorg. Chem., 1986, 25, 4692 CrossRef CAS.
  19. C. J. O'Connor, Prog. Inorg. Chem., 1982, 29, 203 CAS.
Click here to see how this site uses Cookies. View our privacy policy here.