Synthesis and properties of mononuclear tris(heteroleptic) osmium(II) complexes containing bidentate polypyridyl ligands[hair space]

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Erik Z. Jandrasics and F. Richard Keene


Abstract

A general synthetic methodology has been elaborated for tris(bidentate ligand)osmium(II) complexes containing three different polypyridyl ligands. The tris(heteroleptic) complexes were characterized by NMR techniques, and the ligand dependence of their electrochemistry and electronic spectroscopy examined.


References

  1. G. F. Strouse, P. A. Anderson, J. R. Schoonover, T. J. Meyer and F. R. Keene, Inorg. Chem., 1992, 31, 3004 CrossRef CAS.
  2. P. A. Anderson, G. B. Deacon, K. H. Haarmann, F. R. Keene, T. J. Meyer, D. A. Reitsma, B. W. Skelton, G. F. Strouse, N. C. Thomas, J. A. Treadway and A. H. White, Inorg. Chem., 1995, 34, 6145 CrossRef CAS.
  3. P. A. Anderson, G. F. Strouse, J. A. Treadway, F. R. Keene and T. J. Meyer, Inorg. Chem., 1994, 33, 3863 CrossRef CAS.
  4. J. A. Treadway, B. Loeb, R. Lopez, P. A. Anderson, F. R. Keene and T. J. Meyer, Inorg. Chem., 1996, 35, 2242 CrossRef CAS.
  5. D. A. Reitsma and F. R. Keene, J. Chem. Soc., Dalton Trans., 1993, 2859 RSC.
  6. T. J. Rutherford, M. G. Quagliotto and F. R. Keene, Inorg. Chem., 1995, 34, 3857 CrossRef CAS.
  7. T. J. Rutherford and F. R. Keene, unpublished work.
  8. T. J. Rutherford, D. A. Reitsma and F. R. Keene, J. Chem. Soc., Dalton Trans., 1994, 3659 RSC.
  9. J. V. Casper, B. P. Sullivan, E. M. Kober and T. J. Meyer, Chem. Phys. Lett., 1982, 91, 91 CrossRef CAS.
  10. E. M. Kober, J. C. Marshall, W. J. Dressick, B. P. Sullivan, J. V. Casper and T. J. Meyer, Inorg. Chem., 1985, 24, 2755 CrossRef CAS.
  11. E. M. Kober, J. V. Casper, B. P. Sullivan and T. J. Meyer, Inorg. Chem., 1988, 27, 4587 CrossRef CAS.
  12. (a) A. B. P. Lever, Inorg. Chem., 1990, 29, 1271 CrossRef CAS; (b) E. S. Dodsworth, A. A. Vlcek and A. B. P. Lever, Inorg. Chem., 1994, 33, 1045 CrossRef CAS.
  13. A. A. Vlcek, E. S. Dodsworth, W. J. Pietro and A. B. P. Lever, Inorg. Chem., 1995, 34, 1906 CrossRef CAS.
  14. S. S. Fielder, M. C. Osborne, A. B. P. Lever and W. J. Pietro, J. Am. Chem. Soc., 1995, 117, 6990 CrossRef CAS.
  15. D. A. Buckingham, F. P. Dwyer, H. A. Goodwin and A. M. Sargeson, Aust. J. Chem., 1964, 17, 315 CAS.
  16. D. M. P. Mingos and D. R. D. Baghurst, Chem. Soc. Rev., 1991, 20, 1 RSC.
  17. J. P. Collins and W. R. Roper, J. Am. Chem. Soc., 1966, 88, 3504 CrossRef.
  18. F. H. Johannsen, W. Preetz and A. Scheffler, J. Organomet. Chem., 1975, 102, 527 CrossRef CAS.
  19. B. P. Sullivan, J. V. Caspar, S. R. Johnson and T. J. Meyer, Organometallics, 1984, 3, 1241 CrossRef CAS.
  20. D. S. Black, G. B. Deacon and N. C. Thomas, Polyhedron, 1983, 2, 409 CrossRef CAS.
  21. D. S. Black, G. B. Deacon and N. C. Thomas, Aust. J. Chem., 1982, 35, 2445.
  22. E. C. Constable, A. M. W. Cargill Thompson, D. A. Tocher and M. A. M. Daniels, New J. Chem., 1992, 16, 855 Search PubMed.
  23. J. V. Caspar, T. D. Westmoreland, G. H. Allen, P. G. Bradley, T. J. Meyer and W. H. Woodruff, J. Am. Chem. Soc., 1984, 106, 3492 CrossRef CAS.
  24. S. Decurtins, F. Felix, J. Ferguson, H.-U. Güdel and A. Ludi, J. Am. Chem. Soc., 1980, 102, 4102 CrossRef CAS.
  25. F. Felix, J. Ferguson, H.-U. Güdel and A. Ludi, Chem. Phys. Lett., 1979, 62, 153 CrossRef CAS.
  26. F. Felix, J. Ferguson, H.-U. Güdel and A. Ludi, J. Am. Chem. Soc., 1980, 102, 4096 CrossRef CAS.
  27. J. C. Curtis, B. P. Sullivan and T. J. Meyer, Inorg. Chem., 1983, 22, 224 CrossRef CAS.
  28. Y. Ohsawa, K. W. Hanck and M. K. De Armond, J. Electroanal. Chem. Interfacial Electrochem., 1984, 175, 229 CrossRef CAS.
  29. D. P. Rillema and K. B. Mack, Inorg. Chem., 1982, 21, 3849 CrossRef CAS.
  30. D. P. Rillema, C. B. Blanton, R. J. Shaver, D. C. Jackman, M. Boldaji, S. Bundy, L. A. Worl and T. J. Meyer, Inorg. Chem., 1992, 31, 1600 CrossRef CAS.
  31. R. Colton and J. C. Traeger, Inorg. Chim. Acta, 1992, 201, 153 CrossRef CAS.
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