C. Jeff Harlan, Simon G. Bott and Andrew R. Barron
The reaction of [Zr(cp)2Me2]
(cp = η5-C5H5) with
the cubane iminoalane,
[HAl(µ3-NBut)]4, yielded
[(cp)2ZrMe(µ-H)]2 and the alkyl-substituted
iminoalanes
[Al4MeH3(µ3-NBut)4
] 1 and
[Al4Me2H2(µ3-NBut
)4] 2. The dimer
[(cp)2ZrMe(µ-H)]2 decomposes above
60 °C. The methyl–hydride exchange is first order with
respect to each reactant concentration, and
ΔH‡ and
ΔS
‡ have been determined as
104(1) kJ mol-1 and 18.8(4) J K-1
mol-1, respectively. The molecular structures of
[(cp)2ZrMe(µ-H)]2,
[HAl(µ3-NBut)]4,
[MeAl(µ3-NBut)]4 and a
cocrystallization disorder of compounds 1, 2 and
[HAl(µ3-NBut)]4 have been determined
by X-ray crystallography.