Michael J. Parkington, T. Anthony Ryan and Kenneth R. Seddon
New, or improved, syntheses of phosgene, carbonyl bromide chloride and carbonyl bromide fluoride have been elaborated. The NMR (13C, 19F and 17O) and electron impact mass spectra were recorded for COX2 (X = F, Cl or Br), COClF, COBrCl and COBrF; trends in the chemical shifts are analysed in terms of σ and π contributions to the bonding. Attempts to prepare carbonyl diiodide in solution were unsuccessful, and the reasons for this are analysed.