Speciation of trace metals in the environment

(Note: The full text of this document is currently only available in the PDF Version )

Steve J. Hill


Abstract

With the recognition of the importance of metal speciation in many areas of environmental study, there has been a tremendous increase in research to aid our understanding of the role of specific metal species in terms of toxicity, bioavailability, bioaccumulation, mobility and persistence in the environment. In turn this has led to the development of analytical techniques that are both sensitive and specific to meet this challenge. This review provides an overview of trace metal speciation in the environment, an insight into some of the analytical techniques that are suitable for metal speciation studies on environmental samples, and a more detailed look at some selected elements for which the environmental chemistry has now been better characterised.


References

  1. Research trends in the field of environmental analysis, ed. P. Quevauviller and E. A. Maier, European Commission, Brussels, 1994. Search PubMed.
  2. Chemical Speciation in the Environment, ed. A. M. Ure and C. M. Davidson, Blackie Academic and Professional, 1995. Search PubMed.
  3. P. Quevauviller, E. A. Maier and B. Griepink, Quality Assurance for Environmental Analysis, Elsevier, 1995. Search PubMed.
  4. Element speciation in bioinorganic chemistry, ed. S. Caroli, Wiley, 1996. Search PubMed.
  5. L. Ebdon, S. J. Hill and R. Ward, Analyst, 1986, 111, 1113 Search PubMed.
  6. L. Ebdon, S. J. Hill and R. Ward, Analyst, 1987, 112, 1 Search PubMed.
  7. S. J. Hill, M. J. Bloxham and P. J. Worsfold, J. Anal. Atomic Spectrom., 1993, 8, 499 Search PubMed.
  8. R. M. Harrison and S. Rapsomanikis, Environmental Analysis using Chromatography Interfaced with Atomic Spectroscopy, Ellis Harwood, 1989. Search PubMed.
  9. C. M. G. van den Berg, Anal. Chim. Acta, 1991, 250, 265 Search PubMed.
  10. P. M. Bersier, J. Howell and C. Bruntlett, Analyst, 1994, 119, 219 Search PubMed.
  11. Determination of trace elements, ed. Z. B. Alfassi, VCH, Weinheim, 1994. Search PubMed.
  12. A. Kim, S. J. Hill, L. Ebdon and S. Rowland, J. High. Res. Chromatogr., 1992, 15, 665 Search PubMed.
  13. K. Lamble and S. J. Hill, Anal. Chim. Acta, 1996, 334, 261 Search PubMed.
  14. J. Dedina and D. L. Tsaleu, Hydride generation atomic absorption spectrometry, Wiley, 1995. Search PubMed.
  15. L. Ebdon, R. W. Ward and D. A. Leathard, Analyst, 1982, 107, 129 Search PubMed.
  16. W. Cairns, L. Ebdon and S. J. Hill, J. Fresenius, Anal. Chem., 1996, 355, 202 Search PubMed.
  17. G. K. Webster and J. W. Karnahan, Element specific: Chromatographic detection by atomic emission spectroscopy, ed. P. C. Uden, ACS Symp. Ser. No. 479, 1992, 218. Search PubMed.
  18. G. O'Connor, L. Ebdon, E. H. Evans, H. Ding, L. K. Olsen and J. A. Caruso, J. Anal. Atomic Spectrom., 1996, 11, 1151 Search PubMed.
  19. D. C. Baxter and W. Frech, Pure Appl. Chem., 1995, 67, 615 Search PubMed.
  20. R. J. Maguire, Water Poll. Res. J. Can., 1991, 26, 243 Search PubMed.
  21. Hazardous Metals in the Environment, ed. M. Stoeppler, Elsevier, 1992. Search PubMed.
  22. R. Puk and J. H. Weber, Appl. Organomet. Chem., 1994, 8, 293 Search PubMed.
  23. I. L. Marr, C. White, D. Ristau, J. L. Wardell and J. Lomax, Appl. Organomet. Chem., 1997, 11, 11 Search PubMed.
  24. S. J. J. Tsai and S. J. Hsu, Analyst, 1994, 119, 403 Search PubMed.
  25. J. Schwarz, G. Henze and F. G. Thomas, J. Fresenius, Anal. Chem., 1995, 352, 474 Search PubMed.
  26. A. Munoz and A. R. Rodriguez, Electroanalysis, 1995, 7, 674 Search PubMed.
  27. H. M. V. M. Soares and M. T. S. D. Vasconelos, Anal. Chim. Acta, 1994, 293, 261 Search PubMed.
  28. C. Dorey, C. Cooper, D. P. E. Dickson, J. F. Gibson, R. J. Simpson and T. J. Peters, Brit. J. Nutrition, 1993, 70, 157 Search PubMed.
  29. D. L. Clark, S. D. Conradson, S. A. Ekberg, N. J. Hess, D. R. Janecky, M. P. Neu, P. D. Palmer and C. D. Tait, New J. Chem., 1996, 20, 211 Search PubMed.
  30. C. Rivas, L. Ebdon, E. H. Evans and S. J. Hill, Appl. Organomet. Chem., 1996, 10, 61 Search PubMed.
  31. L. Pitts, A. Fisher, P. Worsfold and S. J. Hill, J. Anal. Atomic Spectrom., 1995, 10, 519 Search PubMed.
  32. A. A. Brown, L. Ebdon and S. J. Hill, Anal. Chim. Acta, 1994, 286, 391 Search PubMed.
  33. A. M. Naghmush, K. Pyrznska and M. Trojanowicz, Anal. Chim. Acta, 1994, 288, 247 Search PubMed.
  34. M. J. Tomlinson, L. Lin and J. A. Caruso, Analyst, 1995, 120, 583 Search PubMed.
  35. A. G. Howard and C. Salou, Anal. Chim. Acta, 1996, 333, 89 Search PubMed.
Click here to see how this site uses Cookies. View our privacy policy here.