DOI: 10.1039/A706395D
(Paper)
Reference Section for: Chem. Commun., 1997, 2373-2374
Catalytic and asymmetric aziridination of alkenes catalysed by a chiral manganese porphyrin complex
(Note: The full text of this document is currently only available in the PDF Version )
Tat-Shing Lai, Chi-Ming Che, Hoi-Lun Kwong and Shie-Ming Peng
Abstract
A D4-manganese(III) porphyrin is utilized to catalyze aziridination of styrene-type substrates with enantiomeric excess ranging from 43 to 68%; evidence for a MnIV reactive intermediate in the catalysis was obtained from spectroscopic studies and organic product analysis.
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