Cubic lanthanide sulfido clusters: Ln8S6(SPh)12(thf)8 (Ln = Pr, Nd, Gd)

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Jonathan H. Melman , Thomas J. Emge and John G. Brennan


Abstract

Lanthanide thiolates react with elemental sulfur to give Ln8S6(SPh)12(thf)8 clusters in high yield.


References

  1. (a) D. Cary, G. Ball and J. Arnold, J. Am. Chem. Soc., 1995, 117, 3492 CrossRef CAS; (b) W. Evans, G. Rabe and J. Ziller, Angew. Chem., Int. Ed. Engl., 1994, 33, 2110 CrossRef; (c) D. Freedman, T. J. Emge and J. G. Brennan, J. Am. Chem. Soc., 1997, 119, 11 112 CrossRef CAS.
  2. C. B. Murray, D. J. Norris and M. G. Bawendi, J. Am. Chem. Soc., 1993, 115, 8706 CrossRef CAS; N. Herron, J. Calabrese, W. E. Farneth and Y. Wang, Science, 1993, 259, 1426 CrossRef CAS; M. A. Marcus, W. Flood, M. Steigerwald, L. Brus and M. Bawendi, J. Phys. Chem., 1991, 95, 1572 CrossRef CAS; A. N. Goldstein, C. M. Escher and A. P. Alivisatos, Science, 1992, 256, 1425 CrossRef CAS; B. Schreiner, K. Dehnicke and D. Fenske, Z. Anorg. Allg. Chem., 1993, 619, 1127 CrossRef CAS; N. Herron, A. Duna and Y. Wang, J. Chem. Soc., Dalton Trans., 1992, 15, 2329 RSC.
  3. See, for example: J. Brennan, T. Siegrist, S. Stuczynski and M. Steigerwald, J. Am. Chem. Soc., 1992, 114, 10334 Search PubMed; L. F. Dahl, A. Johnson and S. Whoolery, Inorg. Chem. Acta, 1994, 227, 269 CrossRef CAS; D. Fenske and A. Fischer, Angew. Chem., 1995, 34, 307 CrossRef; P. Mathur and P. Sekar, Chem. Commun., 1996, 727 CAS.
  4. See, for example: (a) B. Cetinkaya, P. B. Hitchcock, M. F. Lappert and R. G. Smith, J. Chem. Soc., Chem. Commun., 1992, 932 RSC; (b) A. R. Strzelecki, C. Likar, B. A. Hesel, T. Utz, M. C. Lin and P. A. Bianconi, Inorg. Chem., 1994, 33, 5188 CrossRef CAS; (c) K. Tatsumi, T. Amemiya, H. Kawaguchi and K. Tani, J. Chem. Soc., Chem. Commun., 1993, 773 RSC; J. Lee, M. Brewer, M. Berardini and J. Brennan, Inorg. Chem., 1995, 34, 3215 CrossRef CAS; K. Mashima, Y. Nakayama, T. Shibahara, H. Fukumoto and A. Nakamura, Inorg. Chem., 1996, 35, 93 CrossRef CAS; M. Berardini and J. Brennan, Inorg. Chem., 1995, 34, 6179 CrossRef CAS; M. Berardini, T. Emge and J. Brennan, J. Am. Chem. Soc., 1993, 115, 8501 CrossRef CAS.
  5. M. Berardini, T. J. Emge and J. G. Brennan, Inorg. Chem., 1995, 34, 5327 CrossRef CAS; J. Lee, T. J. Emge and J. G. Brennan, Inorg. Chem., 1997, 36, 5064 CrossRef CAS.
  6. M. Brewer, J. Lee and J. G. Brennan, Inorg. Chem., 1995, 34, 5919 CrossRef CAS.
  7. See for example: M. Pham-Thi, J. Alloys Compd., 1995, 225, 547 Search PubMed; G. Harkonen, M. Leppanen, E. Soininen, R. Tornquist and J. Viljanen, J. Alloys Compd., 1995, 225, 552 CrossRef CAS; G. Blasse, J. Alloys Compd., 1995, 225, 529 CrossRef; K. Karpinska, M. Godlewski, M. Leskela and L. Niinisto, J. Alloys Compd., 1995, 225, 544 CrossRef CAS; C. R. Ronda, J. Alloys Compd., 1995, 225, 534 CrossRef CAS.
  8. See for example: P. K. Kumta and S. H. Risbud, J. Mater. Sci., 1994, 29, 1135 Search PubMed; J. Nishii, S. Morimoto, R. Yokota and T. Yamagishi, J. Non-Cryst. Solids, 1987, 95/96, 641 CrossRef CAS; J. S. Sanghara, L. E. Busse and I. D. Aggarwall, J. Appl. Phys., 1994, 75, 4885; T. Katsugama and H. Matsumura, J. Appl. Phys., 1994, 75, 2743 CrossRef.
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