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DOI: 10.1039/A706054H (Paper) Reference Section for: Chem. Commun., 1997, 2233-2234

Synthesis of tetrasubstituted derivatives of [Fe3(CO)12]

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Xuetai Chen and Brian E. Mann

Abstract

The treatment of [Fe3(CO)10L1L2] [L1, L2 = CO, P(OMe)3, P(OCH2)3CMe] with CNBut in the presence of Me3NO yields the tetrasubstituted derivatives, [Fe3(CO)8(CNBut)4], [Fe3(CO)8(CNBut)3{P(OMe)3}], [Fe3(CO)8(CNBut3)- {P(OCH2)3CMe}], [Fe3(CO)8(CNBut3)2{P(OCH2)3CMe}2], [Fe3(CO)8(CNBut)2{P(OCH2)3CMe}{P(OMe)3}] and [Fe3- (CO)8(CNBut3)2{P(OMe)3}2]; the compounds were characterised by analysis, mass spectrometry, IR, and (in part) 1H and 31P NMR spectroscopy.

References

  1. M. P. Brown, P. A. Dolby, M. M. Harding, A. J. Mathews and A. K. Smith, J. Chem. Soc., Dalton Trans., 1993, 1671 RSC.
  2. M. I. Bruce, J. G. Matisons, J. M. Patrick, A. H. White and A. C. Willis, J. Chem. Soc., Dalton Trans., 1985, 1223 RSC.
  3. J. S. Field, R. J. Haines and J. A. Jay, J. Organomet. Chem., 1989, 377, C35 CrossRef CAS.
  4. P. J. Roberts and J. Trotter, J. Chem. Soc. A, 1970, 3246 RSC.
  5. M. I. Bruce, M. J. Liddell, O. bin Shawkataly, I. Bytheway, B. W. Skelton and A. H. White, J. Organomet. Chem., 1989, 369, 217 CrossRef CAS.
  6. S.-G. Teoh, H.-K. Fun and O. bin Shawkataly, Z. Kristallogr., 1990, 190, 287 CAS.
  7. S. Cartwright, J. A. Clucas, R. H. Dawson, D. F. Foster, M. M. Harding and A. K. Smith, J. Organomet. Chem., 1986, 302, 403 CrossRef CAS.
  8. H. A. Mirza, J. J. Vittal and R. J. Puddephatt, Inorg. Chem., 1993, 32, 1327 CrossRef CAS.
  9. R. F. Alex, F. W. B. Einstein, R. H. Jones and R. K. Pomeroy, Inorg. Chem., 1987, 26, 3175 CrossRef CAS.
  10. G. Raper and W. S. McDonald, J. Chem. Soc., A, 1971, 3430 RSC.
  11. H. Adams, X. Chen and B. E. Mann, J. Chem. Soc., Dalton Trans., 1996, 2159 RSC.
  12. A. F. Clifford and A. K. Mukherjee, Inorg. Chim. Acta, 1963, 2, 151 CAS; B. F. G. Johnson, Inorg. Chim. Acta, 1986, 115, L39 CrossRef CAS; S. L. Yang, C. S. Li and C. H. Chang, J. Chem. Soc., Chem. Commun., 1987, 1872 RSC; F.-H. Luo, S.-R. Yang, C.-S. Li, J.-P. Duan and C.-H. Cheng, J. Chem. Soc., Dalton Trans., 1991, 2435 RSC.
  13. J.-K. Shen, Y.-L. Shi, Y.-C. Gao, Q.-Z. Shi and F. Basolo, J. Am. Chem. Soc., 1988, 110, 2414 CrossRef CAS; J.-K. Shen, Y.-C. Gao, Q.-Z. Shi and F. Basolo, Inorg. Chim. Acta, 1988, 27, 4236 CAS.
  14. H. Adams, N. A. Bailey, G. W. Bentley and B. E. Mann, J. Chem. Soc., Dalton Trans., 1989, 1831 RSC; S. Aime, M. Botto, O. Gambino, R. Gobetto and D. Osella, J. Chem. Soc., Dalton Trans., 1989, 1277 RSC.
  15. H. Adams, N. A. Bailey, G. W. Bentley and B. E. Mann, J. Chem. Soc., Dalton Trans., 1989, 1831 RSC; B. E. Mann, J. Chem. Soc., Dalton Trans., 1997, 1457 RSC.
  16. H. Adams, A. G. Carr, B. E. Mann and R. Melling, Polyhedron, 1995, 14, 2771 CrossRef CAS.
  17. M. I. Bruce, T. W. Hambley and B. K. Nicholson, J. Chem. Soc., Dalton Trans., 1983, 2385 RSC.
  18. J. B. Murray, B. K. Nicholson and A. J. Whitton, J. Organomet. Chem., 1990, 385, 91 CrossRef CAS.
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