Polycatenated copper(I) molecular ladders: a new structural motif in inorganic coordination polymers

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Alexander J. Blake, Neil R. Champness, Andrei Khlobystov, Wan-Sheung Li, Martin Schröder, Andrei Khlobystov and Dmitri A. Lemenovskii


Abstract

The complex {[Cu2(MeCN)2L3](PF6)2} [L = 1,4-bis(4-pyridyl)butadiyne] is prepared and characterised by X-ray diffraction studies which show an undulating polycatenated molecular ladder structure involving fully interwoven two-dimensional sheets.


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