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DOI: 10.1039/A705415G (Paper) Reference Section for: Chem. Commun., 1997, 2007-2008

First observation of non-bridging thiolates or tetrahedral geometries within thiolate-containing Schiff-base macrocycles: [Zn2L][CF3SO3]2

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Sally Brooker and Tony C. Davidson

Abstract

The structure determination of [Zn2L][CF3SO3]2 1 reveals the first example of non-bridging thiolates within a thiolate-containing Schiff-base macrocyclic complex: the flexibility of such macrocycles is also clearly demonstrated as this is the first example of the provision of distorted tetrahedral metal ion binding sites.

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