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DOI: 10.1039/A705348G (Paper) Reference Section for: Chem. Commun., 1997, 2009-2010

High-nuclearity mixed-metal carbonyl clusters of osmium and palladium; molecular structures of [Os5Pd6(CO)13(µ-CO)5(µ-H)2(µ-dppm)2] ·2CH2Cl2·C6H14 and [Os5Pd6(CO)13(µ-CO)6(µ-dppm)2]

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Janesse Wing-Sze Hui and Wing-Tak Wong

Abstract

The high-nuclearity mixed-metal carbonyl clusters [Os5- Pd6(CO)13(µ-CO)5(µ-H)2(µ-dppm)2] 1 and [Os5Pd6(CO)13- (µ-CO)6(µ-dppm)2] 2 are synthesized from the reaction of [Os3(CO)10(µ-H)2] with [Pd2(µ-dppm)2Cl2]; their molecular structures are determined by X-ray analysis.

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