Hydrogen-bonded porous solid derived from trimesic amide

Abstract

N,N′,N″-Tris(3-pyridyl)trimesic amide, 1, forms a unique P3̄ symmetrical crystal containing pores with a mean diameter of 8.26 Å.

References

1. E. Weber, R. Pollex and M. Czugler, J. Org. Chem., 1992, 57, 4068; D. Venkataraman, S. Lee, J. Zhang and J. S. Moore, Nature, 1994, 371, 591; M. R. Ghadiri, Adv. Mater., 1995, 7, 675.
2. G. B. Gardner, D. Venkataraman, J. S. Moore and S. Lee, Nature, 1995, 374, 792; P. Brunet, M. Simard and J. D. Wuest, J. Am. Chem. Soc., 1997, 119, 2737.
3. V. A. Russell and M. D. Ward, Chem. Mater., 1996, 8, 1654; E. Fan, C. Vicent, S. J. Geib and A. D. Hamilton, Chem. Mater., 1994, 6, 1113.
4. N. Khazanovich, J. R. Granja, D. E. McCree, R. E. Milligan and M. R. Ghadiri, J. Am. Chem. Soc., 1994, 116, 6011; M. D. Ward, Nature, 1995, 374, 764; R. E. Melendez, C. V. Krishnamohan Sharma, M. J. Zarawotko, C. Bauer and R. D. Rogers, Angew. Chem., Int. Ed. Engl., 1996, 35, 2213; M. Mascal, N. M. Hext, R. Warmuth, M. H. Moore and J. P. Turkenburg, Angew. Chem., Int. Ed. Engl., 1996, 35, 2204; R. Bishop, Chem. Soc. Rev., 1996, 311.
5. A. R. A. Palmans, J. A. J. M. Vekemans, H. Fischer, R. A. Hikmet and E. W. Meijer, Chem. Eur. J., 1997, 3, 300.
6. M. C. Etter, Acc. Chem. Res., 1990, 23, 120.
7. Z. Berkovich-Yellin and L. Leiserowitz, Acta Crystallogr., Sect. B, 1984, 40, 1596; G. R. Desiraju, Acc. Chem. Res., 1996, 29, 441.
8. (a) A. Mahdyarfar and K. D. M. Harris, J. Chem. Soc., Chem. Commun., 1993, 51; (b) X. Wang, M. Simard and J. D. Wuest, J. Am. Chem. Soc., 1994, 116, 12119; (c) O. M. Yaghi, G. Li and H. Li, Nature, 1995, 378, 704.
9. D. J. Duchamp and R. E. Marsh, Acta Crystallogr., Sect. B, 1969, 25, 5.
10. S. V. Kolotuchin, E. E. Fenlon, S. R. Wilson, C. J. Loweth and S. C. Zimmerman, Angew. Chem., Int. Ed. Engl., 1995, 34, 2654.
11. A. S. Jessiman, D. D. MacNicol, P. R. Mallinson and I. Vallance, J. Chem. Soc., Chem. Commun., 1990, 1619.