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DOI: 10.1039/A705240E (Paper) Reference Section for: Chem. Commun., 1997, 1903-1904

Hydrogen atoms location in [Re4(µ3-H)4(CO)12] by joint X-ray single-crystal and neutron powder diffraction analysis

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Norberto Masciocchi, Angelo Sironi, Norberto Masciocchi, Giuseppe D’Alfonso, Winfried Kockelmann and Wolfgang Schäfer

Abstract

The hydrogen atom locations in [Re4(µ3-H)4(CO)12] are accurately determined by joint X-ray single-crystal and time-of-flight neutron powder diffraction analysis; this new methodology does not require large crystals of several mm dimensions but only a sizeable amount of monophasic microcrystalline sample.

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