View PDF Version
 
DOI: 10.1039/A704749E (Paper) Reference Section for: Chem. Commun., 1997, 1911-1912

Differing degrees of five-coordination for similar tin atoms in the polymetallic complex [(OC)3Fe[upper bond 1 start][lower bond 1 start](µ-Ph2Ppy)(S[lower bond 1 end]nPh2)(µ-Cl)(S[upper bond 1 end]nClPh2)]

(Note: The full text of this document is currently only available in the PDF Version )

Pierre Braunstein, Chantal Charles, Pierre Braunstein, Chantal Charles, Guido Kickelbick and Ulrich Schubert

Abstract

The unusual iron–bistin complex, [(OC)3F[upper bond 1 start][lower bond 1 start]e(µ-Ph2Ppy)(S[lower bond 1 end]nPh2)(µ-Cl(S[upper bond 1 end]nClPh2)], obtained by silicon–tin exchange from a Si–Fe–Sn precursor, contains two tin atoms showing different degrees of five-coordination, a unique feature of relevance to hypercoordination of main-group elements.

References

  1. A. G. Davies, in Comprehensive Organometallic Chemistry II, ed. E. W. Abel, F. G. A. Stone and G. Wilkinson, vol 2, p. 217 Search PubMed.
  2. H. B. Bürgi and J. D. Dunitz, Acc. Chem. Res., 1983, 16, 153 CrossRef; Structure Correlations, ed. H. B. Bürgi and J. D. Dunitz, VCH, Weinheim, 1994 Search PubMed.
  3. M. S. Holt, W. L. Wilson and J. H. Nelson, Chem. Rev., 1989, 89, 11 CrossRef CAS; J. A. Zubieta and J. J. Zuckerman, Prog. Inorg. Chem., 1978, 24, 251 CAS.
  4. P. Braunstein, C. Charles, A. Tiripicchio and F. Ugozzoli, J. Chem. Soc., Dalton Trans., 1996, 4365 RSC.
  5. G. Reinhard, B. Hirle, U. Schubert, M. Knorr, P. Braunstein, A. DeCian and J. Fischer, Inorg. Chem., 1993, 32, 1656 CrossRef CAS.
  6. (a) P. Braunstein, M. Knorr, M. Strampfer, A. DeCian and J. Fischer, J. Chem. Soc., Dalton Trans., 1994, 117 RSC; (b) M. Knorr, H. Piana, S. Gilbert and U. Schubert, J. Organomet. Chem., 1990, 388, 327 CrossRef CAS; (c) P. Braunstein, C. Charles, R. D. Adams and R. Layland, J. Cluster Sci., 1995, 7, 145; (d) F. W. B. Einstein and R. Restivo, Inorg. Chim. Acta, 1971, 5, 501 CrossRef CAS.
  7. (a) W. Clegg, C. M. J. Grievson and K. Wade, J. Chem. Soc., Chem. Commun., 1987, 969 RSC; (b) J. Vicente, M. T. Chicote, M. C. Ramirez-de-Arellano, G. Pelizzi and F. Vitali, J. Chem. Soc., Dalton Trans., 1990, 279 RSC; (c) A. L. Balch, H. Hope and F. E. Wood, J. Am. Chem. Soc., 1985, 107, 6936 CrossRef CAS; (d) H. Weichmann, J. Meunier-Piret and M. van Meerssche, J. Organomet. Chem., 1986, 309, 267 CrossRef CAS.
  8. (a) J. T. B. H. Jastrzebski, G. van Koten, C. T. Knaap, A. M. M. Schreurs, J. Kroon and A. L. Spek, Organometallics, 1986, 5, 1551 CrossRef CAS; (b) J. T. B. H. Jastrzebski, J. Boersma, P. M. Esch and G. van Koten, Organometallics, 1991, 10, 930 CrossRef CAS; (c) J. T. B. H. Jastrzebski, E. Wehman, J. Boersma, G. van Koten, K. Goubitz and D. Heijdenrijk, J. Organomet. Chem., 1991, 409, 157 CrossRef CAS; (d) S. K. Lee and B. K. Nicholson, J. Organomet. Chem., 1986, 309, 257 CrossRef CAS.
  9. S. E. Johnson, K. Polborn and H. Nöth, Inorg. Chem., 1991, 30, 1410 CrossRef CAS.
  10. SADABS, Program for empirical absorption correction for Siemens area detectors; G. M. Sheldrick, University of Göttingen, 1996.
Click here to see how this site uses Cookies. View our privacy policy here.