Iron–carbene functionalities supported by a macrocyclic ligand: iron–carbon double bond stabilized by tetramethyldibenzotetraazaannulene
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Alain Klose, Euro Solari, Carlo Floriani, Nazzareno Re, Angiola Chiesi-Villa and Corrado Rizzoli
Abstract
We report an unprecedented entry to the chemistry of the iron–carbene functionality supported by an easily available macrocycle.
References
Transition Metal Carbene Complexes,
VCH,
Weinheim,
1983 Search PubMed; W. D. Wulff,
in Advances in Metal–Organic Chemistry,
ed. L. S. Liebeskind,
Jay,
London, vol. 1,
1989,
pp. 209 Search PubMed; J. W. Herndon,
S. U. Tumer,
L. A. McMullen,
J. J. Matasi and
W. F. K. Schnatter,
in Advances in Metal–Organic Chemistry,
ed. L. S. Liebeskind,
Jay,
London, vol. 3,
1994,
pp. 51–95 Search PubMed; Comprehensive Organometallic Chemistry,
ed. G. Wilkinson, F. G. A. Stone and E. W. Abel,
Pergamon,
Oxford, vol. 12,
1995,
ch. 5.1–5.5 Search PubMed.
(a) D. Mansuy, M. Lange, J. C. Chottard, J. F. Bartoli, B. Chevrier and R. Weiss, Angew. Chem., 1978, 90, 828 CrossRefCAS;
(b) P. J. Brothers and J. P. Collman, Acc. Chem. Res., 1986, 19, 209 CrossRefCAS;
(c) D. Mansuy, Pure Appl. Chem., 1987, 59, 759 CrossRefCAS;
(d) I. Artaud, N. Gregoire, J.-P. Battioni, D. Dupre and D. Mansuy, J. Am. Chem. Soc., 1988, 110, 8714 CrossRefCAS;
(e) I. Artaud, N. Gregoire, P. Leduc and D. Mansuy, J. Am. Chem. Soc., 1990, 112, 6899 CrossRefCAS;
(f) D. Mansuy and
J. P. Mahy,
in Metalloporphyrins Catalyzed Oxidations,
ed. F. Montanari and L. Casella,
Kluwer,
Dordrecht,
1994,
p. 175 Search PubMed.
J. P. Collman, P. J. Brothers, L. McElwee-White, E. Rose and L. J. Wright, J. Am. Chem. Soc., 1985, 107, 4570 CrossRefCAS; J. P. Collman, P. J. Brothers, L. McElwee-White and E. Rose, J. Am. Chem. Soc., 1985, 107, 6110 CrossRefCAS.
H. Brand and J. Arnold, Coord. Chem. Rev., 1995, 140, 137 CrossRefCAS; T. Aida and S. Inoue, Acc. Chem. Res., 1996, 29, 39 CrossRefCAS.
J. P. Collman,
L. S. Hegedus,
J. R. Norton and
R. G. Finke,
Principles and Applications of Organotransition Metal Chemistry,
University Science Books,
Mill Valley, CA,
1987 Search PubMed.
(a) T. Boschi, S. Licoccia, R. Paolesse and P. Tagliatesta, Organometallics, 1989, 8, 330 CrossRefCAS;
(b) J.-P. Djukic, D. A. Smith, V. G. Young, Jr. and L. K. Woo, Organometallics, 1994, 13, 3020 CrossRefCAS.
Some leading references to the use of [tmtaa]2– as an ancillary ligand in the organometallic chemistry of the early transition metals are:
(a) C. H. Jang, J. A. Ladd and V. L. Goedken, J. Coord. Chem., 1988, 18, 317;
(b) S. De Angelis, E. Solari, E. Gallo, C. Floriani, A. Chiesi-Villa and C. Rizzoli, Inorg. Chem., 1992, 31, 2520 CrossRefCAS;
(c) L. Giannini, E. Solari, C. Floriani, A. Chiesi-Villa and C. Rizzoli, Angew. Chem., Int. Ed. Engl., 1994, 33, 2204 CrossRef;
(d) L. Giannini, E. Solari, S. De Angelis, T. R. Ward, C. Floriani, A. Chiesi-Villa and C. Rizzoli, J. Am. Chem. Soc., 1995, 117, 5801 CrossRefCAS;
(e) D. G. Black, D. C. Swenson and R. F. Jordan, Organometallics, 1995, 14, 3539 CrossRefCAS;
(f) H. Schumann, Inorg. Chem., 1996, 35, 1808 CrossRefCAS;
(g) G. I. Nikonov, A. J. Blake and P. Mountford, Inorg. Chem., 1997, 36, 1107 CrossRefCAS.
(a) V. L. Goedken, J. J. Pluth, S. M. Peng and B. Bursten, J. Am. Chem. Soc., 1976, 98, 8014 CrossRefCAS;
(b) M. C. Weiss, B. Bursten, S. M. Peng and V. L. Goedken, J. Am. Chem. Soc., 1976, 98, 8021 CrossRefCAS;
(c) V. L. Goedken, S. M. Peng, J. A. Molin-Norris and Y. Park, J. Am. Chem. Soc., 1976, 98, 8391 CrossRefCAS;
(d) M. C. Weiss and V. L. Goedken, Inorg. Chem., 1979, 18, 819 CrossRefCAS;
(e) P. Berno, C. Floriani, A. Chiesi-Villa and C. Guastini, J. Chem. Soc., Dalton Trans., 1988, 1409 RSC;
(f) P. Berno, C. Floriani, A. Chiesi-Villa and C. Guastini, J. Chem. Soc., Dalton Trans., 1989, 551 RSC.
P. E. Riley, R. E. Davis, N. T. Allison and W. M. Jones, Inorg. Chem., 1982, 21, 1321 CrossRefCAS; D. Bauer, P. Härter and E. Herdtweck, J. Chem. Soc., Chem. Commun., 1991, 829 RSC.
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