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DOI: 10.1039/A704174H (Paper) Reference Section for: Chem. Commun., 1997, 1659-1660

A sulfur nitrogen triple, double and single bond in one ligand: synthesis and structure of [Co{N[triple bond, length as m-dash]SF2–N[double bond, length as m-dash]S(O)F2} 4][AsF6]2·SO2

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Reinhard Hoppenheit, Enno Lork, Jan Petersen and Rüdiger Mews

Abstract

NSF2NS(O)F2 reacts quantitatively with [Co(SO2)n][AsF6]2 to give [Co{N[triple bond, length as m-dash]SF2–N[double bond, length as m-dash]S(O)F2} 4][AsF6]2·SO2; X-ray structure analysis confirms the presence of a triple, double and single bond in the same ligand.

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