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DOI: 10.1039/A704124A (Paper) Reference Section for: Chem. Commun., 1997, 1997-1998

Reversible oxidation of [MonW3–n(η5-C5H5)3(CO)6(µ3-P)] (n = 0–3) by sulfur; synthesis and characterisation of [MonW3–n(η5-C5H5)3(CO)6(µ3-PS)] (n = 0–3)

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John E. Davies, Martin J. Mays and Elizabeth J. Pook

Abstract

The trimetallic tetrahedrane complexes [MonW3–n(η5-C5H5)3(CO)6(µ3-P)] (n = 0–3) are oxidised in carbon disulfide solution by elemental sulfur to the corresponding µ3-PS complexes [MonW3–n(η5-C5H5)3(CO)6(µ3-PS)]; the new complexes lose the sulfur atom upon standing in solution at room temp. to regenerate [MonW3–n(η5-C5H5)(CO)6(µ3-P)]; the X-ray crystal structure of [W3(η5-C5H5)3(CO)6(µ3-PS)] is determined.

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