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DOI: 10.1039/A704000H (Paper) Reference Section for: Chem. Commun., 1997, 1653-1654

Preparation and X-ray crystallographic characterisation of the trititanate [Ti3O(µ-OPri)3(OPri)4 {Me2C(O)CH[double bond, length as m-dash]C(O)CH2C(O)Me2 }], a reaction product of [Ti(OPri)4] and propan-2-one

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James V. Barkley, Jason C. Cannadine, Ian Hannaford, Marjorie M. Harding, Alexander Steiner, John Tallon and Robin Whyman

Abstract

Reaction of Ti(OPri)4 with propan-2-one, under initially anhydrous conditions, yields a colourless moisture-sensitive crystalline product which is structurally identified as the trinuclear oxoalkoxide [Ti3O{µ-OPri)3(OPri) 4{Me2C(O)CH[double bond, length as m-dash]C(O)CH2C(O)Me 2}] containing a coordinated C9 ligand derived from the condensation of propan-2-one.

References

  1. V. W. Day, T. A. Eberspacher, Y. Chen, J. Hao and W. Klemperer, Inorg. Chim. Acta, 1995, 229, 391 CrossRef CAS and references therein.
  2. C. S. Rondestvedt, Kirk Othmer Encyclopaedia of Chemical Technology, Wiley-Interscience, New York, 3rd edn., 1983, vol. 23, p. 176 Search PubMed.
  3. G. W. Parshall and S. D. Ittel, Homogeneous Catalysis, Wiley-Interscience, New York, 2nd edn., 1992, ch. 11 Search PubMed.
  4. R. Mahrwald and H. Schick, Synthesis, 1990, 592 CrossRef CAS.
  5. S. Forsen and M. Nilsson, The Chemistry of the Carbonyl Group, ed. J. Zabicky, Interscience, London, 1970, vol. 2, p. 163 Search PubMed.
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