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DOI: 10.1039/A703979D (Paper) Reference Section for: Chem. Commun., 1997, 1879-1880

Stoichiometric assembly of [Sb(PCy)3]2Li6·6HNMe2·2C6H5Me; a highly fluxional antimony(III) phosphinidine complex containing Me2NH ligation of lithium†

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Michael A. Beswick, Jonathan M. Goodman, Alexander D. Hopkins, Michael A. Paver, Paul R. Raithby, Andrew E. H. Wheatley and Dominic S. Wright

Abstract

All of the Me2NH produced by the reaction of [Sb(NMe2)3] with CyP(H)Li (Cy = C6H11) coordinates the Li+ cations of the product [Sb(PCy)3]2Li6·6HNMe2·2C6H5Me 1; the complex contains the first example of a group 15 metal phosphinidine anion {[Sb(PR)3]3–}.

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