View PDF Version
 
DOI: 10.1039/A703891G (Paper) Reference Section for: Chem. Commun., 1997, 1771-1772

Luminescent gold(i) supermolecules with trithiocyanuric acid. Crystal structure, spectroscopic and photophysical properties

(Note: The full text of this document is currently only available in the PDF Version )

Biing-Chiau Tzeng, Chi-Ming Che and Shie-Ming Peng

Abstract

The first example of an ordered array of Au6 clusters with trithiocyanuric acid, [(LAu)(AuPPhMe2)2]2 (H3L = trithiocyanuric acid), is prepared and characterized by X-ray crystallography; it has a two-dimensional structure via intermolecular AuI···AuI interactions and possesses photoluminescence properties; the ability of trithiocyanuric acid to act as a bridging ligand for molecular assembly of two-dimensional polymeric solids is demonstrated.

References

  1. (a) S.-J. Shieh, X. Hong, S.-M. Peng and C.-M. Che, J. Chem. Soc., Dalton Trans., 1994, 3067 RSC; (b) B.-C. Tzeng, K.-K. Cheung and C.-M. Che, Chem. Commun., 1996, 1681 RSC; (c) B.-C. Tzeng, C.-M. Che and S.-M. Peng, J. Chem. Soc., Dalton Trans., 1996, 1769 RSC.
  2. (a) H. Schmidbaur, Chem. Soc. Rev., 1995, 391 RSC; (b) W. Schneider, A. Bauer and H. Schmidbaur, Organometallics, 1996, 15, 5445 CrossRef; (c) H.-K. Yip, A. Schier, J. Riede and H. Schmidbaur, J. Chem. Soc., Dalton Trans., 1994, 2333 RSC; (d) M. Nakamoto, A. Schier and H. Schmidbaur, J. Chem. Soc., Dalton Trans., 1993, 1347 RSC.
  3. D. M. P. Mingos, J. Yau, S. Menzer and D. J. Williams, Angew. Chem., Int. Ed. Engl., 1995, 34, 1894 CrossRef CAS.
  4. (a) P. M. V. Calcar, M. M. Olmstead and A. L. Balch, J. Chem. Soc., Chem. Commun., 1995, 1773 RSC; (b) P. M. V. Calcar, M. M. Olmstead and A. L. Balch, Chem. Commun., 1996, 2597 RSC.
  5. (a) M. J. Irwin, G. Jia, N. C. Payne and R. J. Puddephatt, Organometallics, 1996, 15, 51 CrossRef CAS; (b) M. J. Irwin, L. M. Muir, K. W. Muir, R. J. Puddephatt and D. S. Yufit, Chem. Commun., 1997, 219 RSC.
  6. (a) M. Contel, J. Garrido, M. C. Gimeno, P. G. Jones, A. Laguna and M. Laguna, Organometallics, 1996, 15, 4939 CrossRef CAS; (b) R. Narayanaswamy, M. A. Young, E. Parkhurst, M. Ouellette, M. E. Kerr, D. M. Ho, R. C. Elder, A. E. Bruce and M. R. M. Bruce, Inorg. Chem., 1993, 32, 2506 CrossRef CAS.
  7. R. M. Dávila, A. Elduque, T. Grant, R. J. Staples and J. P. Fackler, Jr., Inorg. Chem., 1993, 32, 1749 CrossRef CAS.
  8. (a) C.-M. Che, H.-L. Kwong and C.-K. Poon, J. Chem. Soc., Dalton Trans., 1990, 3215 RSC; (b) C.-M. Che, H.-L. Kwong, V. W.-W. Yam and K.-C. Cho, J. Chem. Soc., Chem. Commun., 1989, 885 RSC; (c) C. King, J. C. Wang, M. N. I. Khan and J. P. Fackler, Jr., Inorg. Chem., 1989, 28, 2145 CrossRef CAS.
  9. W. B. Jones, J. Yuan, R. Narayanaswamy, M. A. Young, R. C. Elder, A. E. Bruce and M. R. M. Bruce, Inorg. Chem., 1995, 34, 1996 CrossRef CAS.
Click here to see how this site uses Cookies. View our privacy policy here.