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DOI: 10.1039/A703797J (Paper) Reference Section for: Chem. Commun., 1997, 1739-1740

Remarkable ‘edge’ ligation of a triphosphacyclopentenyl ring system. Synthesis, crystal and molecular structure of [Ni(η5-P3C2But2 ){η2-P3C2But 2CH(SiMe3)2Me}]

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Vinicius Caliman, Peter B. Hitchcock and John F. Nixon

Abstract

In the nickel(II) complex [Ni(η5-P3C2But2 )(η2-P3C2But2 CH(SiMe3)2Me}] the triphosphacyclopentenyl ring P3C2But2CH(SiMe3) 2Me is unexpectedly coordinated to the metal exclusively via the two adjacent saturated ring phosphorus atoms, rather than via the 2-phosphaallyl fragment.

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