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DOI: 10.1039/A703568C (Paper) Reference Section for: Chem. Commun., 1997, 1639-1640

Extraordinary acceleration of phosphodiester hydrolyses by thorium cations

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Robert A. Moss, Jing Zhang and Kathryn Bracken

Abstract

ThIV cations in aqueous Brij micelles strongly promote the hydrolyses of several phosphodiester substrates; in the case of bis(p-nitrophenyl)phosphate 1, the observed rate constant (0.028 s-1) represents an acceleration of ca 2.8 billion.

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