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DOI: 10.1039/A703324I (Paper) Reference Section for: Chem. Commun., 1997, 2235-2236

Approaching a cluster of aluminium(III) selenide: [Al4Se5(H)2(NMe3)4]

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Peter D. Godfrey, Colin L. Raston, Vicki-Anne Tolhurst, Peter D. Godfrey, Brian W. Skelton and Allan H. White

Abstract

The reaction of trans-[{Me3N(H)Al(µ-Se)}2] with N,N,N′,N″,N″-pentamethyldiethylenetriamine (pmdeta) in toluene affords the tetranuclear, alane selenide cluster [Al4Se5(H)2(NMe3)4] (structurally authenticated and ab initio modelled), and with PhTeTePh yields a mixed chalcogenide trans-[{Me3N(PhTe)Al(µ-Se)}2].

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