DOI: 10.1039/A703201C
(Paper)
Reference Section for: Chem. Commun., 1997, 1327-1328
Hydrozirconation of an η2-ligated phosphaalkyne. A new synthetic route to η2-ligated phosphaalkenes
(Note: The full text of this document is currently only available in the PDF Version )
Maria Helena A. Benvenutti, Nathalie Cenac and John F. Nixon
Abstract
The phosphaalkyne complex
[Pt(dppe)(η2-ButC![[triple bond, length as m-dash]](https://www.rsc.org/images/entities/char_e002.gif)
P)] undergoes ready
hydrozirconation with
[ZrHCl(η5-C5H5)2] to give
the metallaphosphaalkene complex
[Pt(dppe){η2-ButCH![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
PZrCl(η
5-C5H5)2}] which is a
useful precursor for the synthesis of η2-phosphaalkene
complexes.
References
- R. B. Bedford, A. F. Hill and C. Jones, Angew. Chem., Int. Ed. Engl., 1996, 35, 547 CrossRef CAS.
- R. B. Bedford, A. F. Hill, C. Jones, A. J. P. White, D. J. Williams and J. D. E. T. Wilton-Ely, Chem. Commun., 1997, 179 RSC.
- J.-P. Majoral, M. Zablocka, A. Igau and N. Cenac, Chem. Ber., 1996, 129, 879 CrossRef CAS.
- L. Weber, Angew. Chem., Int. Ed. Engl., 1996, 35, 271 CrossRef CAS.
- M. H. A. Benvenutti, N. Cenac, S. D'Arbeloff and J. F. Nixon, paper in preparation.