Synthesis of µ-oxo-bridged group 15 element–aluminium heterodinuclear porphyrins [(oep)(Me)M–O–Al(oep)]ClO4 (M=P, As, Sb) and X-ray crystal structure of [(oep)(Me)As–O–Al(oep)]ClO4

(Note: The full text of this document is currently only available in the PDF Version )

Go Yamamoto, Ryo Nadano, Wataru Satoh, Yohsuke Yamamoto and Kin-ya Akiba


Abstract

µ-Oxo-bridged group 15 element–aluminium heterodinuclear porphyrins, [(oep)(Me)M–O–Al(oep)]ClO4 (M=P, As, Sb), are synthesized by the reaction of [(oep)(Me)M(OH)]- ClO4 with (oep)AlMe.


References

  1. For recent reports: K. M. Kadish, M. Autret, Z. Ou, P. Tagliatesta, T. Boschi and V. Fares, Inorg. Chem., 1997, 36, 204 Search PubMed; J. A. Hays, C. L. Day, V. G. Young, Jr. and L. K. Woo, Inorg. Chem., 1996, 35, 7601 CrossRef CAS.
  2. B. Cheng, J. D. Hobbs, P. G. Debrunner, J. Erlebacher, J. A. Shelnutt and W. R. Scheidt, Inorg. Chem., 1995, 34, 102 CrossRef CAS.
  3. M. Takeuchi, T. Imada and S. Shinkai, J. Am. Chem. Soc., 1996, 118, 10658 CrossRef CAS.
  4. Y. Yamamoto, R. Nadano, M. Itagaki and K.-y. Akiba, J. Am. Chem. Soc., 1995, 117, 8287 CrossRef CAS.
  5. W. Satoh, R. Nadano, Y. Yamamoto and K.-y. Akiba, Chem. Commun., 1996, 2451 RSC.
  6. K.-y. Akiba, Y. Onzuka, M. Itagaki, H. Hirota and Y. Yamamoto, Organometallics, 1994, 13, 2800 CrossRef CAS; K. M. Kadish, M. Autret, Z. Ou, K.-y. Akiba, S. Masumoto, R. Wada and Y. Yamamoto, Inorg. Chem., 1996, 35, 5564 CrossRef CAS.
  7. N. Takeda and S. Inoue, Bull. Chem. Soc. Jpn., 1978, 51, 3564 CAS.
  8. R. Guilard, M. A. Lopez, A. Tabard, P. Richard, C. Lecomte, S. Brandes, J. E. Hutchison and J. P. Collman, J. Am. Chem. Soc., 1992, 114, 9877 CrossRef CAS.
  9. H. Matsuda, T. Taga, K. Osaki, H. Sugimoto, M. Mori and H. Ogoshi, J. Am. Chem. Soc., 1981, 103, 2199 CrossRef.
  10. Z. Otwinowski, University of Texas, Southwestern Medical Center.
Click here to see how this site uses Cookies. View our privacy policy here.