Porous clay heterostructures (PCH) as acid catalysts

(Note: The full text of this document is currently only available in the PDF Version )

Anne Galarneau, Anis Barodawalla and Thomas J. Pinnavaia


Abstract

Porous clay heterostructures formed by surfactant assembly of open framework silica in the galleries of a smectite clay represent a new family of solid acid catalysts, as evidenced by the selective dehydration of 2-methylbut-3-yn-2-ol to 2-methylbut-3-yn-1-ene.


References

  1. F. Figueras, Catal. Rev.-Sci. Eng., 1988, 30, 457 Search PubMed.
  2. Y. Izumi, K. Urabe and M. Onaka, Zeolite, Clay, and Heteropoly Acid in Organic Reactions, VCH Publishers, 1992, pp. 49–98 Search PubMed.
  3. A. Galarneau, A. Barodawalla and T. J. Pinnavaia, Nature, 1995, 374, 529 CrossRef CAS.
  4. J. S. Beck, J. C. Vartuli, W. J. Roth, M. E. Leonowicz, C. T. Kresge, K. D. Schmitt, C. T.-W. Chu, D. H. Olson, E. W. Sheppard, S. B. McCullen, J. B. Higgins and J. L. Schlenker, J. Am. Chem. Soc., 1992, 114, 10 834 CrossRef CAS.
  5. C. T. Kresge, M. E. Leonowicz, W. J. Roth, J. C. Vartuli and J. S. Beck, Nature, 1992, 359, 710 CrossRef CAS.
  6. H. Laron-Pernot, F. Luck and J. M. Popa, Appl. Catal., 1991, 78, 213 CrossRef CAS.
  7. J.-R. Butruille and T. J. Pinnavaia, Catal. Today, 1992, 14, 141 CrossRef.
  8. J.-R. Butruille, L. J. Michot and T. J. Pinnavaia, J. Catal., 1993, 139, 664 CrossRef CAS.
  9. E. P. Parry, J. Catal., 1963, 2, 371 CrossRef CAS.
Click here to see how this site uses Cookies. View our privacy policy here.