View PDF Version
 
DOI: 10.1039/A703035E (Paper) Reference Section for: Chem. Commun., 1997, 1657-1658

[(p-PriC6H4Me)4 Ru4Mo4O16]: an amphiphilic organoruthenium oxomolybdenum cluster presenting a unique framework geometry

(Note: The full text of this document is currently only available in the PDF Version )

Georg Süss-Fink, Laurent Plasseraud, Vincent Ferrand and Helen Stoeckli-Evans

Abstract

The amphiphilic title compound, easily accessible from (p- cymene)ruthenium dichloride dimer and sodium molybdate in aqueous solution, presents an unprecedented Ru4Mo4O12 framework comprising a central Mo4O4 cube with four folded ORuO flaps resembling the sails of a windmill.

References

  1. V. W. Day and W. G. Klemperer, Science, 1985, 228, 533 CrossRef CAS.
  2. K. Isobe and A. Yagasaki, Acc. Chem. Res., 1993, 26, 524 CrossRef CAS.
  3. R. K. C. Ho and W. G. Klemperer, J. Am. Chem. Soc., 1978, 100, 6772 CrossRef CAS.
  4. H. K. Chae, W. G. Klemperer and V. W. Day, Inorg. Chem., 1989, 28, 1424 CrossRef; H. K. Chae, W. G. Klemperer, D. E. Paez Loyo, V. W. Day and T. A. Ebersbacher, Inorg. Chem., 1991, 31, 3187; H. K. Chae, W. G. Klemperer and T. A. Marquart, Coord. Chem. Rev., 1993, 128, 209 CrossRef CAS.
  5. (a) Y. Hayashi, K. Toriumi and K. Isobe, J. Am. Chem. Soc., 1988, 110, 3666 CrossRef CAS; (b) Y. Do, X.-Z. You, C. Zhang, Y. Ozawa and K. Isobe, J. Am. Chem. Soc., 1991, 113, 5892 CrossRef CAS; (c) Y. Hayashi, Y. Ozawa and K. Isobe, Inorg. Chem., 1991, 30, 1025 CrossRef CAS; (d) J. T. Park, T. Nishioka, T. Suzuki and K. Isobe, Bull. Chem. Soc. Jpn., 1994, 67, 1968 CAS.
  6. Y. Lin, K. Nomiya and R. G. Finke, Inorg. Chem., 1993, 32, 6040 CrossRef CAS; A. Trovarelli and R. G. Finke, Inorg. Chem., 1993, 32, 6034 CrossRef CAS; M. Pohl and R. G. Finke, Organometallics, 1993, 12, 1453 CrossRef CAS; B. M. Rapko, M. Pohl and R. G. Finke, Inorg. Chem., 1994, 33, 3625 CrossRef CAS; M. Pohl, D. K. Lyon, N. Mizuno, K. Nomiya and R. G. Finke, Inorg. Chem., 1995, 34, 1413 CrossRef CAS; K. Nomiya, Ch. Nozaki, M. Kaneko, R. G. Finke and M. Pohl, J. Organomet. Chem., 1995, 505, 23 CrossRef CAS; M. Pohl, Y. Lin, T. J. R. Weakley, K. Nomiya, M. Kaneko, H. Weiner and R. G. Finke, Inorg. Chem., 1995, 34, 767 CrossRef CAS.
  7. C. L. Hill and C. M. Prosser-McCartha, Coord. Chem. Rev., 1995, 143, 407 CrossRef CAS.
  8. G. M. Sheldrick, Acta Crystallogr., Sect. A, 1990, 46, 467 CrossRef.
  9. G. M. Sheldrick, Program for Crystal Structure Refinement, Universität Göttingen, 1993.
  10. N. Walker and D. Stuart, Acta Crystallogr., Sect. A, 1990, 39, 158 CrossRef.
  11. C. K. Johnson, ORTEP, Oak Ridge National Laboratory, Oak Ridge TN, 1976; modified by L. Zolnai and H. Pritzkow, Universität Heidelberg, 1994.
Click here to see how this site uses Cookies. View our privacy policy here.