DOI: 10.1039/A703009F
(Paper)
Reference Section for: Chem. Commun., 1997, 1301-1302
Exploiting a substituted dihydrotriazinide as a novel bulky ligand: synthesis and crystal structure of a rubidium complex with an unprecedented tetrameric cyclic core
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William Clegg, Allison M. Drummond, Robert E. Mulvey and Paul O’Shaughnessy
Abstract
A metal exchange reaction between the alkoxide ButORb and a dihydrotriazinidolithium complex in tetrahydrofuran (thf) has yielded the first reported triazinidorubidium species, in the bis(thf) solvate of 4-n-butyl-4-tert-butyl-2,6-diphenyl-1,4-dihydro-s -triazinido-1-rubidium, which exists as a unique cyclic tetramer in the solid state having an unprecedented sixteen-membered (NCNRb)4 ring core.
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