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DOI: 10.1039/A703007J (Paper) Reference Section for: Chem. Commun., 1997, 1485-1486

A new manganese cluster topology capable of yielding high-spin species: mixed-valence [Mn7(OH)3Cl3(hmp)9]2 + with S ≥ 10

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Milissa A. Bolcar, Sheila M. J. Aubin, Kirsten Folting, David N. Hendrickson and George Christou

Abstract

The reaction between MnCl2·4H2O, Hhmp (Hhmp = 2-hydroxymethylpyridine) and NEt4MnO4 in MeCN gives NEt4[Mn7(OH)3Cl3(hmp)9 ]Cl[MnCl4] 1; the 4 MnII, 3 MnIII cation comprises a Mn6 hexagon containing a central Mn ion, and it possesses a S ≥ 10 ground state.

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