Vanadium complexes of the N(CH2CH2S)33- ligand with co-ligands relevant to nitrogen fixation processes

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Sian C. Davies, David L. Hughes, Zofia Janas, Lucjan Jerzykiewicz, Raymond L. Richards, J. Roger Sanders and Piotr Sobota


Abstract

Vanadium(III) and vanadium(V) complexes of the tris(2-thiolatoethyl)amine ligand L3- containing hydrazine, hydrazide, imide, ammine, cyanide and isocyanide ligands are synthesised; the complexes [V(NH3)L] and [V(NNMe2)L] have been structurally characterised.


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