A novel pentadentate ligand 2,6-bis[methoxybis(2-pyridyl)methyl]pyridine L for mononuclear iron(ii) and manganese(ii) compounds; synthesis and crystal structures of [FeL(MeCN)][ClO4]2 and [(MnL(H2O)][ClO4]2

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Maartje E. de Vries, Rene M. La Crois, Gerard Roelfes, Huub Kooijman, Anthony L. Spek, Ronald Hage and Ben L. Feringa


Abstract

A novel pentadentate ligand L is capable of stabilising FeII and MnII centres, the first of which gives a transient iron hydroperoxide species upon treatment with hydrogen peroxide.


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