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DOI: 10.1039/A702788E (Paper) Reference Section for: Chem. Commun., 1997, 1341-1342

A tetranickel(ii) macrocyclic complex incorporating five different bridging groups

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Paul E. Kruger and Vickie McKee

Abstract

The synthesis and crystal structure of the tetranickel(II) complex [Ni4(L1)(OH)(MeCO2)3(MeCO 2H)] is reported, where H4L1 is a macrocyclic ligand incorporating thiophenolate, alkoxo and imine donors; the faces of the tetranickel array are differentiated and two of the nickel ions share three monatomic bridges (S,O,O).

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